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Class of organic compounds
A thioamide (rarely, thionamide, but also known as thiourylenes) is a functional group with the general structure R1−C(=S)−NR2R3, where R1, R2 and R3
Thioamide
Chemical compound
annually. NMP reacts with phosphorus pentasulfide to give its analogous thioamide. With sodium hydroxide NMP undergoes reversible ring opening, yielding
N-Methyl-2-pyrrolidone
Chemical compound
an organosulfur compound that is used antithyroid preparation. It is a thioamide, closely related to propylthiouracil. Methylthiouracil is not used clinically
Methylthiouracil
Chemical compound
the synthesis of organic and inorganic compounds. It is a prototypical thioamide. Thioacetamide is known to induce acute or chronic liver disease (fibrosis
Thioacetamide
Chemical prefix denoting the replacement of an oxygen atom with sulfur
(Indo-European dh-w) and may have originally meant "fumigation substance".) Thioamide Thiocyanate Thioether Thioketone Thiol Thiophene Thiourea Thiosulfate
Thio-
Compound derived from an acid
flavorings and fragrances which aim to mimic those odors. List of esters Amide Thioamide Carboximidate Carbamate IUPAC, Compendium of Chemical Terminology, 5th
Ester
Chemical compound
called 2-imidazolidinethione and mercaptobenzothiazole, which is also a thioamide. It is prepared from o-phenylenediamine. Form, G. R.; Raper, E. S.; Downie
Mercaptobenzimidazole
Topics referred to by the same term
osmosensory transporter Prop-, a prefix in chemistry Propylthiouracil (PROP), a thioamide drug Prop (rugby league), a rugby league position Prop (rugby union),
Prop_(disambiguation)
Chemical compound
whereas thiocyanuric acid is yellow. It can also be viewed as a trimeric thioamide. It is a planar molecular as determined by X-ray crystallography. Like
Thiocyanuric_acid
Excessive production of thyroid hormone
including: intravenous beta blockers such as propranolol, followed by a thioamide such as methimazole, an iodinated radiocontrast agent or an iodine solution
Hyperthyroidism
Chemical compound
Sulazepam is a benzodiazepine derivative. It is the thioamide derivative of diazepam. It is metabolised into diazepam, desmethyldiazepam and oxydiazepam[citation
Sulazepam
Species of flowering plant
an oxazolidin-2-one, formed via the 2-thione and without formation of thioamide" (PDF). Phytochemistry. 153: 79–93. Bibcode:2018PChem.153...79A. doi:10
Reseda_luteola
Chemical compound
of a 1,2,4-triazole heterocycle with three functional groups: amine, thioamide and hydrazyl. X-ray crystallography shows that this molecule is polar
4-Amino-3-hydrazino-5-mercapto-1,2,4-triazole
4-Amino-3-hydrazino-5-mercapto-1,2,4-triazole
Chemical compound
Benzylthiouracil (BTU) is an antithyroid preparation. It is a thioamide, closely related to propylthiouracil. Benzylthiouracil has been associated with
Benzylthiouracil
Enzyme expressed mainly in the thyroid gland
stimulated by TSH, which upregulates gene expression. TPO is inhibited by the thioamide drugs, such as propylthiouracil and methimazole. In laboratory rats with
Thyroid_peroxidase
Chemical compound
effect (similarly to naproxcinod) trimebutine thiocarbamoylbenzoate – thioamide group acts as a hydrogen sulfide donor, also acting as an anti-inflammatory
Trimebutine
Chemical compound
2-hydroxypyridine, 2-mercaptopyridine converts to the thione (or more accurately thioamide) tautomer. The preferred form is dependent on temperature, concentration
2-Mercaptopyridine
Chemical compound
pregnancy is not recommended as safety is unclear. Ethionamide is in the thioamides family of medications. It is believed to work by interfering with the
Ethionamide
Mosaic genetic disorder affecting the bone, skin and endocrine systems
screen for cancer. Hyperthyroidism is managed with medications such as thioamides. However, because hyperthyroidism in McCune–Albright syndrome does not
McCune–Albright_syndrome
Chemical compound
formula HC(S)NH2. Although lightly studied, it is of interest as the parent thioamide. The structure has been confirmed by X-ray crystallography, which reveals
Thioformamide
Chemical reaction
elemental sulfur and an amine like morpholine. The initial product is a thioamide for example that of acetophenone which can again be hydrolyzed to the
Willgerodt_rearrangement
Chemical compound
(Trimeglamide) Trimethobenzamide Trimetozine Tritiozine (ala trimetozine but thioamide). Trocimine [14368-24-2] Troxipide (Lefron) Troxonium Troxypyrrolium (Troxypyrrole
Eudesmic_acid
Organosulfur compounds of the form R–SC(=O)–R′
thionoester with an alcohol under base-catalyzed conditions. Xanthates and thioamides can be transformed to thionoesters under metal-catalyzed cross-coupling
Thioester
Chemical compound
Dover LG, Besra GS, Jacobs WR, et al. (January 2007). "Mechanism of thioamide drug action against tuberculosis and leprosy". The Journal of Experimental
Protionamide
Chemical compound
4-diazepin-2-one [100827-80-3] (6). The amide carbonyl is converted to a thioamide with phosphorus pentoxide giving, Methyl 3-[5-(2-chlorophenyl)-2-sulfanylidene-1
Apafant
Chemical compound
structures. As an electrophile, it can react with other nucleophiles to form thioamide types of structures, some of which can undergo subsequent reactions to
Trimethylsilyl_isothiocyanate
Chemical compound
(2019). "Role of Staple Molecules in the Formation of S···S Contact in Thioamides: Experimental Charge Density and Theoretical Studies". Crystal Growth
2-Imidazolidinethione
Chemical compound
the Barton–McCombie deoxygenation. Other uses include the synthesis of thioamides and thiocarbamates. Like the analogous CDI, it may be used for peptide
Thiocarbonyldiimidazole
Medical condition
version. Hyperthyroidism caused by Graves' disease may be treated with the thioamide drugs propylthiouracil, carbimazole or methimazole, or rarely with Lugol's
Thyroid_disease
Organosulfur compound (S=C(NH2)2)
[C2H4(SC(NH2)2)2]Br2 + 2 KOH → C2H4(SH)2 + 2 OC(NH2)2 + 2 KBr Like other thioamides, thiourea can serve as a source of sulfide upon reaction with metal ions
Thiourea
Benzodiazipine
Quazepam, sold under the brand name Doral among others, is a relatively long-acting benzodiazepine derivative drug developed by the Schering Corporation
Quazepam
Chemical compound
hyperthyroidism, particularly when they are used as an adjunctive therapy with thioamides (propylthiouracil, carbimazole). They can be used in the treatment of
Iopanoic_acid
Chemical process
Atom Size Dictates the Hydrogen-Bond Donor Capability of Carboxamides, Thioamides, and Selenoamides". Chemistry – A European Journal. 28 (31) e202200755
Thiourea_organocatalysis
Chemical compound
unclear.[citation needed] Conversion of the amide in trimetozine to the thioamide gives Tritiozine. Swiss Pharmaceutical Society (2000). Index Nominum 2000:
Trimetozine
Type of organocatalysis
Atom Size Dictates the Hydrogen-Bond Donor Capability of Carboxamides, Thioamides, and Selenoamides". Chemistry – A European Journal. 28 (31) e202200755
Hydrogen-bond_catalysis
Chemical compound
Hantzsch thiazole synthesis, which is a reaction between haloketones and thioamides. For example, 2,4-dimethylthiazole is synthesized from thioacetamide and
Thiazole
Pharmaceutical compound
Thiomyristoyl is a drug which acts as a potent sirtuin 2 (SIRT2) inhibitor. It inhibits SIRT2 with an IC50 of 28 nM, though its activity at other SIRT
Thiomyristoyl
Disease treatment
group 3): e.g., ciprofloxacin (CIP), levofloxacin, moxifloxacin (MXF) thioamides (WHO group 4): e.g. ethionamide, prothionamide cycloserine (WHO group
Management_of_tuberculosis
Chemical compound
Dithiooxamide, also known as rubeanic acid, is an organic compound. It is the sulfur analog of oxamide. It acts as a chelating agent, e.g. in the detection
Dithiooxamide
Organic compounds that contain sulfur
A are prominent in biochemistry, especially in fatty acid synthesis. Thioamides, with the formula R1C(=S)N(R2)R3 are more common than thioketones and
Organosulfur_chemistry
Stereoisomerism due to hindered rotation
analogues of biphenyl. Some acylic systems, such as amides and especially thioamides, also exhibit the phenomenon owing to the partial double bond character
Atropisomer
Chemical compound
imides are converted to the corresponding thiocarbonyls. Amides give thioamides. With 1,4-diketones the reagent forms thiophenes. P4S10 is also used to
Phosphorus_pentasulfide
Chemical compound containing carbon and at least one halogen
that excessive stores of TH accumulate, slowing the onset of action of thioamides (TH synthesis blockers). In addition, the functionality of iodides fades
Halocarbon
covalently-linked nickel-pincer nucleotide (NPN) cofactor (pyridinium 3-thioamide-5-thiocarboxylic acid mononucleotide), where the nickel atom is bound
Lactate_racemase
Constants that describe stability of coordination complexes
"Selective complexation of soft Pb2+ and Hg2+ by a novel allyl functionalized thioamide calix[4]arene in 1,3-alternate conformation: a UV-visible and H-1 NMR
Stability constants of complexes
Stability_constants_of_complexes
Organic chemical reaction
viable. In addition to alkyl and aryl thioesters; (hetero)aryl sulfides, thioamides, sulfanyl alkynes, and thiocyanates are competent electrophiles. Virtually
Liebeskind–Srogl_coupling
Chemical compound
(2019). "Palladium-catalyzed Suzuki-Miyaura coupling of thioureas or thioamides". Nature Communications. 10 (1): 5709. Bibcode:2019NatCo..10.5709M. doi:10
4-Trifluoromethylbenzaldehyde
Chemical compound
TC OT 39 is a non-peptide partial agonist of the oxytocin and vasopressin V2 receptors (Ki = 147 nM and >1000 nM, respectively) and antagonist of the vasopressin
TC_OT_39
"soft" sulfur donor atoms, whereas Tp− has three nitrogen donor atoms. The thioamide sulfur is highly basic, as found for other thioureas. The TmR anion simulates
Tm_ligands
(2012). Direct recognition and quantification by volammetry of thiol/thioamide mixes in seawater. Talanta, 89: 496-504. Sidenius U, Skonberg C, Olsen
Environmental impact of silver nanoparticles
Environmental_impact_of_silver_nanoparticles
Functional group in organic chemistry
to heterocycles. Thiazoles arise from reaction of chloroacetone with thioamides.2-Aminothiazoles are similarly produced by reaction of 2-chloroketones
Α-Halo_ketone
Chemical compound
as isothiazoline. Thiazolines were first prepared by dialkylation of thioamides by Richard Willstatter in 1909. 2-Thiazolines are commonly prepared from
Thiazoline
similar to the monothioic and carboxylic acids. Thus amines ammonolyze to thioamides or amidines, hydrazines to thio-hydrazides, and hydroxylamines to thio-hydroxamic
Dithiocarboxylic_acid
Chemical compound
benzanilide with phosphorus pentasulfide or Lawesson's reagent gives thioamide. Oxidative ring formation by reaction with potassium ferricyanide and
Fostedil
Chemical compound
Fimasartan is a non-peptide angiotensin II receptor antagonist (ARB) used for the treatment of hypertension and heart failure. Through oral administration
Fimasartan
Class of chemical compounds
in polar organic solvents. Thiuram monosulfides feature a pair planar thioamide subunits linked by a sulfur atom. Thiuram monosulfides can be prepared
Thiuram_monosulfides
Chemical compound
(CH3CH2−O−)2P(=S)−O−C6H4−NO2 + NaCl PSCl3 reacts with tertiary amides to generate thioamides. For example: C6H5−C(=O)−N(−CH3)2 + PSCl3 → C6H5−C(=S)−N(−CH3)2 + POCl3
Thiophosphoryl_chloride
Chemical compound
Tolrestat (INN; AY-27773) is an aldose reductase inhibitor which was approved for the control of certain diabetic complications. While it was approved
Tolrestat
Organosulfur compounds with an >NC(=S)N< structure
Atom Size Dictates the Hydrogen-Bond Donor Capability of Carboxamides, Thioamides, and Selenoamides". Chemistry – A European Journal. 28 (31) e202200755
Thioureas
Organic reaction where amide is converted to Amine or Aldehyde
polymethylhydrosiloxane has been reported. Lawesson's reagent converts amides to thioamides, which can also be converted into amines. Some amides can be reduced to
Amide_reduction
Pharmaceutical compound
LIT-002 is a small-molecule oxytocin receptor agonist which is under investigation for potential medical use. It is a highly potent full agonist of the
LIT-002
Hormone antagonist acting upon thyroid hormones
with the amino acid tyrosine. The most common drugs in this class are thioamides, which include propylthiouracil, methimazole and its prodrug carbimazole
Antithyroid_agent
Class of chemical compounds
reaction rate. Imidoyl chlorides react with hydrogen sulfide to produce thioamides: RC(NR’)Cl + H2S → RC(S)NHR’ + HCl When amines are treated with imidoyl
Imidoyl_chloride
Amines, alcohols, and thiols displace the chloride to form (respectively) thioamides, thionoesters, and dithioesters. Friedel-Crafts reaction thioacylate arenes
Thioacyl_chloride
Umbrella term covering different chemical reactions
organosulfur chemistry, sulfiding is often called thiation. The preparation of thioamides from amides involves thiation. A typical reagent is phosphorus pentasulfide
Sulfidation
Organic compounds with the structure >C=C=S
stabilized thioketene. Thioketenes are electrophilic. They add amines to give thioamides: R2C=C=S + HNR'2 → R2CH−C(S)−NR'2 With peroxyacids, they produce thioketene-S-oxides:
Thioketene
Chemical compound
2-Indolinethione is an organic compound with the formula C8H6(S)(NH). It is a derivative of dihydroindole containing a thione group. The compound is a
2-Indolinethione
Chemical compound
linkage, a tripeptide intermediate was coupled to a phthaloyl-protected thioamide via mercury-mediated condensation using mercury (II) trifluoromethanesulfonate
Bottromycin
Pharmaceutical compound
YC8-02 is a drug which acts as a potent inhibitor of the enzymes sirtuin 2 (SIRT2) and sirtuin 3 (SIRT3). It was developed from an older SIRT2 selective
YC8-02
The following is a partial list of the "D" codes for Medical Subject Headings (MeSH), as defined by the United States National Library of Medicine (NLM)
List_of_MeSH_codes_(D02)
Catalyst composed of nickel and boron
which are cleaved by hydrogenolysis: The NiCl2/NaBH4 system desulfurizes thioamides, thioethers, thioesters, thiols and sulfides. Organic sulfides, disulfides
Nickel_boride_catalyst
Chemical compound
Chlorthiamide is an organic compound with the chemical formula C7H5Cl2NS used as an herbicide. Chlorthiamide in the Pesticide Properties DataBase (PPDB)
Chlorthiamide
THIOAMIDE
THIOAMIDE
THIOAMIDE
THIOAMIDE
Boy/Male
Indian, Punjabi, Sikh
Forever Aware of the Self
Girl/Female
Gujarati, Hindu, Indian, Kannada, Malayalam, Marathi, Telugu
Fairy
Boy/Male
Arabic, Muslim, Pashtun
Young
Boy/Male
Afghan, Arabic, Australian, Muslim
Accounter; Omnipotent; Another Name of Allah
Male
English
Anglicized form of Irish Gaelic Dáire, DERRY means "fertile, fruitful."
Girl/Female
Arabic, Australian
Peace
Girl/Female
Indian, Punjabi, Sikh
A Winner
Girl/Female
Tamil
By the mind
Boy/Male
Hindu, Indian
Countless
Girl/Female
Muslim
Walking with proud, Swinging gait, Pretty
THIOAMIDE
THIOAMIDE
THIOAMIDE
THIOAMIDE
THIOAMIDE