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Chemical compound
Dimethylformamide, DMF is an organic compound with the chemical formula HCON(CH3)2. Its structure is HC(=O)−N(−CH3)2. Commonly abbreviated as DMF (although
Dimethylformamide
Common synthetic polymer
white, brittle solid. It is soluble in ketones, chlorinated solvents, dimethylformamide, THF and DMAc. PVC was synthesized in 1872 by German chemist Eugen
Polyvinyl_chloride
Organic compounds of the form RC(=O)NR′R″
(H−C(=O)−NH2), acetamide (H3C−C(=O)−NH2), benzamide (C6H5−C(=O)−NH2), and dimethylformamide (H−C(=O)−N(−CH3)2). Amides are qualified as primary, secondary, and
Amide
Chemical compound
It also belongs to the class of dipolar aprotic solvents such as dimethylformamide and dimethyl sulfoxide. It is used in the petrochemical, polymer and
N-Methyl-2-pyrrolidone
Chemical compound
colorless compound, it is a useful high temperature solvent akin to dimethylformamide. It has been used as a formylating agent. Bipp, H.; Kieczka, H. (2012)
N-Formylmorpholine
Chemical compound
chloride is also obtained in high yield (95%) in the reaction of dimethylformamide (DMF) with dimethylcarbamoyl chlorideThe conversion of DMF with thionyl
N,N,N′,N′-Tetramethylformamidinium chloride
N,N,N′,N′-Tetramethylformamidinium_chloride
Chemical compound
N-diisopropylethylamine), or triethylamine to form amide bonds. Typically dimethylformamide is used as solvent, although other polar aprotic solvents can also
HATU
Chemical compound
from the N,N-dimethylformamide catalyzed reaction, dimethylcarbamoyl chloride, is a potent carcinogen, stemming from the N,N-dimethylformamide decomposition
Oxalyl_chloride
Chemical compound
highly soluble in dichloromethane, tetrahydrofuran, acetonitrile and dimethylformamide, but insoluble in water. The C−N=C=N−C core of carbodiimides (N=C=N)
N,N'-Dicyclohexylcarbodiimide
Chemical compound
Deuterated dimethylformamide ((CD3)2NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH3)2NCOH) in which the hydrogen atom ("H") is replaced
Deuterated_DMF
Chemical compound of hydrogen and oxygen
glycerol, 1,4-dioxane, tetrahydrofuran, sulfolane, acetaldehyde, dimethylformamide, dimethoxyethane, dimethyl sulfoxide, acetonitrile. Partially miscible
Water
Chemical compound
1'-Azobis(N,N-dimethylformamide); N,N,N′,N′-Tetramethylazobisformamide; Azodicarboxylic acid bis(dimethylamide); 1,1'-Azobis(N,N-dimethylformamide) Identifiers
Tetramethylazodicarboxamide
Type of soft foam toy
they all release unacceptable levels of harmful substances, such as dimethylformamide, leading to their removal from the Danish market and the recommendation
Squishy
Chemical compound
Vilsmeier reaction or Vilsmeier-Haack reaction that use mixtures of dimethylformamide and phosphorus oxychloride to generate the Vilsmeier reagent, which
Vilsmeier_reagent
CH3NO, simplest amide
Formamides are compounds of the type RR′NCHO. One important formamide is dimethylformamide, (CH3)2NCHO. In the past, formamide was produced by treating formic
Formamide
Chemical compound
dipolar solvent. It is an environmentally friendly alternative to dimethylformamide (DMF) and N-methyl-2-pyrrolidone (NMP). Dihydrolevoglucosenone can
Dihydrolevoglucosenone
Molecules whose atoms interchange between symmetric positions
the four CO ligands. A classic example of a fluxional molecule is dimethylformamide (DMF). At temperatures near 100 °C, the 500 MHz 1H NMR spectrum of
Fluxional_molecule
Chemical compound
(CH3)2C4H2O. Although often abbreviated DMF, it should not be confused with dimethylformamide. A derivative of furan, this simple compound is a potential biofuel
2,5-Dimethylfuran
Chemical compound
dimethylacetamide: N-Methylacetamide Dimethylformamide Munro, D. D.; Stoughton, R. B. (1965). "Dimethylacetamide (DMAC) and Dimethylformamide (DMFA). Effect on Percutaneous
Dimethylacetamide
Chemical reaction
[1][2][3] The first step is the formation of an enamine 2 using N,N-dimethylformamide, dimethyl acetal and pyrrolidine.[4] The desired indole 3 is then
Leimgruber–Batcho indole synthesis
Leimgruber–Batcho_indole_synthesis
Analytical method in electrochemistry
mechanism of organic electrochemistry. Anthracene in deoxygenated dimethylformamide (DMF) will be reduced (An + e− -> An−) at the electrode surface that
Chronoamperometry
Chemical compound
described, because they worked at ambient temperature in anhydrous dimethylformamide (DMF) solvent. Working in DMSO solvent does not allow isolation of
Wieland–Miescher_ketone
Chemical compound
NMF is closely related to other formamides, notably formamide and dimethylformamide (DMF). However, industrial use and production of NMF are far less
N-Methylformamide
Chemical compound
insoluble in cold water, and insoluble in ethanol. When dissolved in dimethylformamide, its absorption maximum lies at about 442 nm. It is usually supplied
Lithol_Rubine_BK
Chemical compound
temperature. DMCC can also be formed in small amounts (up to 20 ppm) from dimethylformamide (DMF) in the Vilsmeier–Haack reaction or when DMF is used as a catalyst
Dimethylcarbamoyl_chloride
Steroid medication
20 {\displaystyle [\alpha ]_{D}^{20}} +65° to +72° cm3/dm·g (1% in dimethylformamide). In 2010, Teva and Perrigo launched the first generic inhalable triamcinolone
Triamcinolone
pyramidalization on the nitrogen atom (59° compared to 0 for reference dimethylformamide) and torsion around the carbon-nitrogen bond to an extent of 91°.
Quinuclidone
Chemical compound
in place of the two hydrogens. It is used in place of the related dimethylformamide for niche applications. Diethylformamide may be prepared industrially
Diethylformamide
Chemical process for converting aromatic chlorides to fluorides
anhydrous potassium fluoride. Typical solvents are dimethylsulfoxide, dimethylformamide, and sulfolane. Potassium chloride is generated in the process. The
Halex_process
Class of chemical compounds
from 0.8 g/mL at 20 °C to 0.3 g/mL at 80 °C for [CH3NH3]PbBr3 in dimethylformamide. This property is used in the growth of MALH single crystals and films
Methylammonium_lead_halide
Chemical compound with formula NaCl
glycol 71 Formic acid 52 Liquid ammonia 30.2 Methanol 14 Ethanol 0.65 Dimethylformamide 0.4 Propan-1-ol 0.124 Sulfolane 0.05 Butan-1-ol 0.05 Propan-2-ol 0
Sodium_chloride
Chemical compound
pyridinium cations. The Cornforth reagent is readily soluble in water, dimethylformamide and dimethyl sulfoxide (DMSO). It is poorly soluble in acetone and
Cornforth_reagent
2-Dichloroethene Arsenic 1982–1984 Testicular cancer Fulton County, New York 3 Dimethylformamide (DMF) 2-Ethoxyethanol 2-Ethoxyethyl acetate 2-Butoxyethanol 1987–1999
List_of_cancer_clusters
Chemical compound
with better hydrocarbon solubility than other amide solvents such as dimethylformamide (DMF). It has also been used to transfer the formyl group to a Grignard
N-Formylpiperidine
Index of chemical compounds with the same molecular formula
C3H7NO may refer to: Acetone oxime (acetoxime) 1-Amino-2-propanone Dimethylformamide Isoxazolidine N-Methylacetamide Oxazolidine Propionamide This set
C3H7NO
Substance dissolving a solute resulting in a solution
CH3-C(=O)-O-CH2-CH3 77.1 6.02 0.894 1.78 Acetone CH3-C(=O)-CH3 56.1 21 0.786 2.88 Dimethylformamide (DMF) H-C(=O)N(CH3)2 153 38 0.944 3.82 Acetonitrile (MeCN) CH3-C≡N
Solvent
Chemical compound
yellow solid with low solubility in water but good solubility in dimethylformamide. The existence of two isomers of PtCl2(NH3)2 led Alfred Werner to
Transplatin
Class of enzymes
(EC 3.5.1.56) is an enzyme that catalyzes the chemical reaction N,N-dimethylformamide + H2O ⇌ {\displaystyle \rightleftharpoons } dimethylamine + formate
N,N-dimethylformamidase
Chemical compound
this reaction uses sodium nitrite in either a dimethyl sulfoxide or dimethylformamide solvent. Via condensations like the Henry reaction, nitroethane converts
Nitroethane
Chemical compound
created at the Buna Werke Schkopau (Polyacrylonitrile) and Leuna works (Dimethylformamide). In the same year, the collective was awarded the GDR's National
Polyacrylonitrile
Polar solvent with a low tendency to donate hydrogen ions
(CH3)2NCOCH3 165 °C 37.8 0.94 g/cm3 3.72 reacts with strong acids and bases dimethylformamide (CH3)2NCHO 153 °C 36.7 0.95 g/cm3 3.86 reacts with strong acids and
Polar_aprotic_solvent
Hydrocarbon compound (HC≡CH)
of acetylene in acetone is 27.9 g per kg. For the same amount of dimethylformamide (DMF), the solubility is 51 g. At 20.26 bar, the solubility increases
Acetylene
Chemical compound
also be used to demethylate quaternary ammonium salts by heating in dimethylformamide (DMF). It is produced by thermal reactions of compounds of the type
DABCO
Solvent used to dissolve paint
called nail varnish remover Butanone / methyl ethyl ketone (MEK) Dimethylformamide (DMF) Glycol ethers — such as 2-Butoxyethanol Alcohols — such as isopropyl
Paint_thinner
Chemical compound
be produced by the reaction of palladium(II) sulfide and oxygen in dimethylformamide. When anhydrous palladium(II) sulfate absorbs moisture from the air
Palladium(II)_sulfate
Thermoplastic fluoropolymer
case of solution-based processing, typical solvents used include dimethylformamide and the more volatile butanone. In aqueous emulsion polymerization
Polyvinylidene_fluoride
Measure of Lewis basicity
methanol 19 kcal/mol (79 kJ/mol) tetrahydrofuran 20 kcal/mol (84 kJ/mol) dimethylformamide (DMF) 26.6 kcal/mol (111 kJ/mol) dimethyl sulfoxide (DMSO) 29.8 kcal/mol
Donor_number
Chemical compound
water 2605 g/L (15 °C) Solubility in ethanol 110 g/L Solubility in dimethylformamide 119.6 g/L Solubility in dimethyl sulfoxide 361.7 g/L Solubility in
Caesium_carbonate
Chemical reaction
ortho to the aryl halide, although this typically requires use of dimethylformamide (DMF) as solvent. Stephens, R. D.; Castro, C. E. (1963). "The Substitution
Castro–Stephens_coupling
Catalyst composed of nickel and boron
whenever NiCl2/NaBH4 is used in dimethylformamide as sodium borohydride may spontaneously ignite in dimethylformamide. Cobalt boride Urushibara nickel
Nickel_boride_catalyst
Chemical reaction
formyl group is called a formylating agent. These include: Formic acid Dimethylformamide and phosphorus oxychloride, in the Vilsmeier-Haack reaction. Hexamethylenetetramine
Formylation
Chemical compound
triphenylphosphine and a carbon monoxide source. The most popular method uses dimethylformamide (DMF) as a solvent, and sometimes aniline is added to accelerate the
Vaska's_complex
Medical condition
Kazunori; Watanabe, Takao; Ikeda, Masayuki (1992-01-01). "Occupational dimethylformamide exposure". International Archives of Occupational and Environmental
Alcohol_intolerance
Copper-promoted cross-coupling reactions
high-boiling, polar solvents such as N-methylpyrrolidone, nitrobenzene, or dimethylformamide and high temperatures (often in excess of 210 °C) with stoichiometric
Ullmann_condensation
Porous substrate used to transport and store acetylene
metal cylinders filled with agamassan, which is half-filled with dimethylformamide (DMF) or acetone. The acetylene is dissolved in the DMF or acetone
Agamassan
Chemical compound
the Phase III subjects. Condensation of 4-Acetylpyridine with N,N-Dimethylformamide dimethyl acetal (DMFDMA) gives the "enamide" (3). This is then condensed
Ocinaplon
Chemical compound
emission wavelength shifts from 380 nm in cyclohexane to 450 nm in N,N-dimethylformamide to 498 nm in methanol to 520 nm in water. Cyclic voltammetry shows
Prodan_(dye)
Military incapacitating agent
is soluble in water, soluble in dilute acids, trichloroethylene, dimethylformamide, and most organic solvents, and insoluble with aqueous alkali. Structurally
3-Quinuclidinyl_benzilate
Chemical compound
the ketone. For instance, with a slurry of sodium hydride in THF or dimethylformamide (DMF), the base only reacts at the solution–solid interface. A ketone
Lithium_diisopropylamide
Potassium compound and alternative to salt
41 Methanol 5.3 Ethanol 0.37 Formic acid 192 Sulfolane 0.04 Acetonitrile 0.024 Acetone 0.00091 Formamide 62 Acetamide 24.5 Dimethylformamide 0.17–0.5
Potassium_chloride
Pharmaceutical compound
active ingredient of which is the highly toxic industrial solvent dimethylformamide. Michelle Olga Patricia Visser, working as a medical technician at
Virodene
diethylenetriamine 111–40–0 C4H10O2 dimethoxyethane 110–71–4 (CH3)2NC(O)H dimethylformamide 68–12–2 C2H8N2 1,1-dimethylhydrazine 57–14–7 C2H8N2 1,2-dimethylhydrazine
List of water-miscible solvents
List_of_water-miscible_solvents
Probable carcinogens
Dieldrin, and aldrin metabolized to dieldrin Dimethylcarbamoyl chloride Dimethylformamide 1,2-Dimethylhydrazine Dimethyl sulfate Doxorubicin Epichlorohydrin
IARC_group_2A
Chemical compound
by reaction of ethanethiol with a suspension of sodium hydride in dimethylformamide. Ethanethiol can be oxidized to ethyl sulfonic acid, using strong
Ethanethiol
Reaction in organic chemistry
original Hajos-Parrish procedure begins with an achiral triketone in dimethylformamide and 3% (molar) catalytic (S)‑(−)‑proline. The product is a chiral
Proline-catalyzed aldol reactions
Proline-catalyzed_aldol_reactions
Association of molecules of a solvent with molecules or ions of a solute
solvents. From left to right: Water, Methanol, Ethanol, Acetonitrile, Dimethylformamide, Acetone, Ethylacetate, Dichloromethane n-Hexane, Methyl tert-butyl
Solvation
Device used in chemical laboratories
water (100 °C at standard atmospheric pressure, 760 torr or 1 bar), dimethylformamide (DMF, 153 °C at the same), or dimethyl sulfoxide (DMSO, 189 °C at
Rotary_evaporator
Type of fast-acting adhesive
softening cured cyanoacrylate. Other solvents include nitromethane, dimethylformamide, dimethyl sulfoxide, and methylene chloride. Another viable solvent
Cyanoacrylate
Organosulfur chemical compound used as a solvent
solvent and is less toxic than other members of this class, such as dimethylformamide, dimethylacetamide, N-methyl-2-pyrrolidone, and hexamethylphosphoramide
Dimethyl_sulfoxide
Chemical compound
essential. Methyl formate is used primarily to manufacture formamide, dimethylformamide, and formic acid. These compounds are precursors or building blocks
Methyl_formate
Organic chemical compound
presence of the water-binding reagent 2-cyanopyridine and the solvent dimethylformamide DMF at 150 °C, 40 MPa CO2 pressure and 5 h reaction time gives in
Glycerol-1,2-carbonate
Chemical compound
equivalent of silver nitrate is added to a solution of cisplatin in dimethylformamide. The mixture is stirred at 55 °C away from light and the resulting
Phenanthriplatin
Chemical compound
the substance which then need to be further purified. The solvents dimethylformamide and dimethylacetamide are derived from dimethylamine. It is raw material
Dimethylamine
Chemical compound
"Explosion Hazards of Sodium Hydride in Dimethyl Sulfoxide, N,N-Dimethylformamide, and N,N-Dimethylacetamide". Organic Process Research & Development
Sodium_hydride
Organic reaction that involves loss of CO
undergo decarbonylation, even without adding a catalyst. For instance, dimethylformamide ((CH3)2NC(O)H) slowly decomposes to give dimethylamine and carbon
Decarbonylation
Chemical compound
dissolves very well in water as well as other polar solvents, e.g., Dimethylformamide, acetonitrile. Texas Red, attached to a strand of DNA or RNA, can
Texas_Red
Organic compound with a –C(=O)Cl group
acids with thionyl chloride (SOCl2). The reaction is catalyzed by dimethylformamide and other additives. Thionyl chloride is a well-suited reagent as
Acyl_chloride
Reaction in organic chemistry
is conducted in unreactive polar aprotic solvents such as ether, dimethylformamide(DMF) or tetrahydrofuran (THF). In efforts to improve the reaction
Wurtz_reaction
Class of chemical substance
5-benzene tricarboxylic acid tris [N-(4-pyridyl)amide], dmf = N,N-dimethylformamide) constructed by tridentate amide linkers and cadmium salt catalyzes
Metal–organic_framework
Chemical compound
(155 °C) Solubility in ethanediol 3.46 g/100 g (20 °C) Solubility in dimethylformamide 0.5 g/kg Magnetic susceptibility (χ) −4.1·10−5 cm3/mol Refractive
Sodium_carbonate
Chemical compound
organolithium reagent n-butyllithium followed by quenching with N,N-dimethylformamide (DMF) to create the aldehyde. 1,2-Ethanediol was added to this structure
NanoPutian
Chemical compound
in polar aprotic solvents such as dimethyl sulfoxide (DMSO), N,N-Dimethylformamide (DMF), and N-Methyl-2-pyrrolidone (NMP) Hazards GHS labelling: Pictograms
FOX-7
Chemical coupling reaction
with moderate to high selectivity. If the reaction is performed in dimethylformamide in the presence of lithium iodide or sodium iodide, the product is
Wittig_reaction
Turkish company
The catalyst 2,2'-Azobis(2-methylpropionitrile), with the solvents dimethylformamide, dimethylacetamide, dimethylsulfoxide and dimethylsulphone were detected
Aksa_(company)
Chemical compound
framework can be substituted with other ligands, such as pyridine and dimethylformamide. Many different salts are known by exchanging the anion, e.g.
Iron(III)_acetate
Chemical compound
with water, as well as donor solvents such as dimethyl sulfoxide and dimethylformamide. Disulfuryl chloride Trisulfuryl chloride Patnaik, P. (2002). Handbook
Sulfuryl_chloride
TMAO Chemical compound
(CH3)3NO The dihydrate is dehydrated by azeotropic distillation from dimethylformamide. Trimethylamine oxide is used in protein folding experiments to counteract
Trimethylamine_N-oxide
Chemical compound
concentrated sulfuric acid. Cathodic reduction of bromotrifluoromethane in dimethylformamide with aluminium as anode gives high yields of fluoral. In this reaction
Fluoral
Synthetic fiber made from polymer
fiber is produced by dissolving the polymer in a solvent such as N,N-dimethylformamide (DMF) or aqueous sodium thiocyanate, metering it through a multi-hole
Acrylic_fiber
Base-labile protecting group
deprotection is performed with a solution of 20% piperidine in N,N-dimethylformamide (DMF). C13H9−CH2−OC(O)NHR + (CH2)5NH → (CH2)5NH+2 + [C13H8−CH2−OC(O)NHR]−
Fluorenylmethyloxycarbonyl protecting group
Fluorenylmethyloxycarbonyl_protecting_group
Chemical element with atomic number 55 (Cs)
"Complexation of caesium and rubidium cations with crown ethers in N,N-dimethylformamide". Polyhedron. 15 (21): 3897–3903. doi:10.1016/0277-5387(96)00018-6
Caesium
Chemical compound
characteristics to polymers. Solubility: AMPS is very soluble in water and dimethylformamide (DMF) and also shows limited solubility in most polar organic solvents
2-Acrylamido-2-methylpropane sulfonic acid
2-Acrylamido-2-methylpropane_sulfonic_acid
Topics referred to by the same term
DMF may refer to: Dimethylformamide, a common solvent Dimethyl fumarate, a small molecule anti-inflammatory human medicine 2,5-Dimethylfuran, a liquid
DMF
Anion composed of boron with 4 nitrate groups
It also dissolves in liquid ammonia, acetonitrile, methanol, and dimethylformamide. It reacts with liquid sulfur dioxide. At room temperature tetramethylammonium
Tetranitratoborate
Chemical compound
to be soluble in polar organic solvents such as acetonitrile and dimethylformamide. Examples include the tetraphenylphosphonium perrhenate ([PPh4]+[ReO4]−)
Tetraphenylphosphonium chloride
Tetraphenylphosphonium_chloride
Chemical compound
enolate-isonitrile, which can be trapped by silylation. Formylation with dimethylformamide gives 2-formyloxazole. Electrophilic aromatic substitution takes place
Oxazole
German artificial leather
21 April 2023. Retrieved 2 February 2024. "Greener Alternatives to Dimethylformamide Use in Polyurethane Synthetic Leather" (PDF). Archived (PDF) from
Presstoff
Bulgarian physical chemist
Investigation of the Adsorption of Naphthalene and Biphenyl on Mercury from Dimethylformamide solutions. Electrokhimiya 6 (1970) 1359; Soviet Electrochemistry,
Miliana_Kaisheva
useful precursor to other organic compounds and an aerosol propellant Dimethylformamide organic compound; a common solvent for chemical reactions Dimethylsulfide
List_of_reagents
principles and trends are illustrated by the case of complexes of dimethylformamide (DMF), a very common amide ligand. Amides bind to metals through oxygen
Transition metal carboxamide complex
Transition_metal_carboxamide_complex
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