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Chemical compound
Oxalyl chloride is an organic chemical compound with the formula Cl−C(=O)−C(=O)−Cl. This colorless, sharp-smelling liquid, the diacyl chloride of oxalic
Oxalyl_chloride
Class of organic compounds
a multiplicative prefix before -yl and chloride. oxalic acid or ethanedioic acid ((COOH)2) → oxalyl chloride or ethanedioyl dichloride ((COCl)2) adipic
Acyl_chloride
Inorganic compound (SOCl2)
thionyl chloride could be used to make acid anhydrides and acyl chlorides from carboxylic acids and to make alkyl chlorides from alcohols. Oxalyl chloride Phosphorus
Thionyl_chloride
Organic redox reaction
alcohol (−OH) is oxidized to an aldehyde (−CH=O) or ketone (>C=O) using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine
Swern_oxidation
Chemical compound
colorless liquid is prepared by reaction of sodium fluoride with oxalyl chloride. Oxalyl fluoride is being investigated for use in etching as a replacement
Oxalyl_fluoride
Toxic gaseous compound (COCl2)
Bis(trifluoromethyl) disulfide Carbonyl bromide Carbonyl fluoride Oxalyl chloride Perfluoroisobutene Thionyl chloride Thiophosgene Merck Index, 11th Edition, 7310. Nomenclature
Phosgene
Organochlorine compound (C7H5ClO)
chlorides, it can be generated from the parent acid and standard chlorinating agents such as phosphorus pentachloride, thionyl chloride, and oxalyl chloride
Benzoyl_chloride
Simplest dicarboxylic acid. (COOH)2
(m.p. 52.5 to 53.5 °C, 126.5 to 128.3 °F). It forms an acid chloride called oxalyl chloride. Transition metal oxalate complexes are numerous, e.g. the
Oxalic_acid
Chemical compound
heterocycles. Cyanuric chloride can also be used as an alternative to oxalyl chloride in the Swern oxidation. Thiazyl chloride trimer – structural analogue
Cyanuric_chloride
Chemical compound
chlorinating agents including oxalyl chloride and thionyl chloride. This compound undergoes the reactions common for acid chlorides. For example, it reacts
Acryloyl_chloride
Chemical synthesis route
Speeter–Anthony synthesis of triptamines (Scheme 20).94 Indole is acylated with oxalyl chloride to 92, next followed by amide 93 formation and global reduction with
Speeter–Anthony_route
Chemical compound
thionyl chloride to the corresponding acyl chloride. The tendency towards DMCC formation depends on the chlorination reagent (thionyl chloride > oxalyl chloride
Dimethylcarbamoyl_chloride
Chemical compound
such as: Thionyl chloride (SOCl2) Phosphorus pentachloride (PCl5) Oxalyl chloride ((COCl)2) A typical synthesis using thionyl chloride is: CH3(CH2)4COOH
Hexanoyl_chloride
Class of chemical compounds
can however be prepared from dimethyl sulfoxide by treatment with oxalyl chloride. Thiosulfonate also refers to the thiosulfonate anion R−S2O−2 and its
Thiosulfonate
Organic compound (C8H8) with a cube carbon structure
stabilize the cubene intermediate as a ketone (or equivalent) tautomer. Oxalyl chloride oxidizes cubane carboxamides to give a norcubane-furanone derivative
Cubane
Chemical compound
vinylene carbonate, which is used in polymers and in organic synthesis. Oxalyl chloride is produced commercially from ethylene carbonate. Photochlorination
Ethylene_carbonate
Chemical group (–N=C=O)
precautions. A laboratory-safe variation masks the phosgene as oxalyl chloride. Also, oxalyl chloride can form acyl isocyanates from primary amides, which phosgene
Isocyanate
Chemical compound
activator for the Pummerer rearrangement. It can be used in place of oxalyl chloride in the Swern oxidation, allowing temperatures up to −30 °C. With sodium
Trifluoroacetic_anhydride
Organic reaction in chemistry
which uses a catalytic amount of phosphine that is regenerated with oxalyl chloride. The Appel reaction begins with the formation of the phosphonium salt
Appel_reaction
Chemical compound
decomposition of certain oxalates and certain chemoluminescent reactions of oxalyl chloride. 1,2-dioxetanedione α-acetolactone Paolo Strazzolini; Alberto Gambi;
Oxalic_anhydride
Psychedelic drug
encountered synthetic routes are through the reaction of indole with oxalyl chloride followed by reaction with dimethylamine and reduction of the carbonyl
Dimethyltryptamine
Chemical compound
Paolo Strazzolini and others synthesized this compound by reacting oxalyl chloride (COCl)2 or the bromide (COBr)2 with a suspension of silver oxalate
Dioxane_tetraketone
ISBN 0911910123. Allen, C. F. H.; Byers Jr., J. R.; Humphlett, W. J. (1963). "Oleoyl chloride". Organic Syntheses; Collected Volumes, vol. 4, p. 739.; Rutenberg, M.
List_of_reagents
Organosulfur chemical compound used as a solvent
related alcohols to carbonyls by dimethyl sulfoxide "activated" by oxalyl chloride". J. Org. Chem. 43 (12): 2480–2482. doi:10.1021/jo00406a041. DMSO can
Dimethyl_sulfoxide
Reactions in organic chemistry
reactions that produce oxindoles from anilines and α-haloacid chlorides (or oxalyl chloride). The first step is an amide coupling, while the second step
Stollé_synthesis
Organic compound with a –C≡N functional group
dehydrated using aluminum chloride and sodium iodide in acetonitrile. Likewise, both classes can be dehydrated with oxalyl chloride and catalytic dimethyl
Nitrile
Chemical compound
biradical intermediate. It is an intermediate in a reaction (between oxalyl chloride and hydrogen peroxide in ethyl acetate, accumulating in solution at
1,2-Dioxetanedione
Chemical compound
prepared from tetramethylurea using a chlorinating agent such as oxalyl chloride, thionyl chloride or phosphorus oxychloride followed by a salt metathesis reaction
TCFH
Chemical compound
proceeds (in the variant with trifluoroacetic anhydride instead of oxalyl chloride) with a yield of 73%. Under UV irradiation, ketones react with vinylene
Vinylene_carbonate
Chemical production of a pharmaceutical drug
as a result of the deprotection was then converted to an acyl chloride by oxalyl chloride and a catalytic amount of DMF. Finally, addition of sodium azide
Oseltamivir_total_synthesis
2932-78-7 C3H3Br3O2 methyl tribromoacetate 3222-05-7 C3H3ClO3 methyl oxalyl chloride 5781-53-3 C3H3F3N2O2 trifluoroacetylurea 760-41-8 C3H3F5O methyl pentafluoroethyl
List of compounds with carbon number 3
List_of_compounds_with_carbon_number_3
Chemical compound
chloride if the imine becomes protonated. The reaction is typically performed at room temperature. If reagents milder than SOCl2 are required, oxalyl
Oxazoline
Chemical compound
photochlorination of ethylene carbonate. It has been used as precursor for oxalyl chloride. Tetrachloroethylene carbonate acts as a Lewis base and it forms a
Tetrachloroethylene_carbonate
Chemical reaction
iodosyl-based oxidants have been developed, e.g. IBX. Swern oxidation uses oxalyl chloride, dimethylsulfoxide, and an organic base, such as triethylamine. The
Alcohol_oxidation
Chemical compound
isatins. In this case primary or secondary arylamines are condensed with oxalyl chloride to form a chlorooxalylanilide intermediate which can then cyclize in
Isatin
Organic reaction that involves loss of CO
like formyl chloride (−COCl), undergo spontaneous decarbonylation at room temperature (or below). Reactions involving oxalyl chloride (COCl)2 (e.g.
Decarbonylation
Chemical compound
including its conversion to the acid chloride cyclohexanecarbonyl chloride using thionyl chloride or oxalyl chloride and to various other acyl derivatives
Cyclohexanecarboxylic_acid
27156-03-2 C2Cl2O2 oxalyl chloride 79-37-8 C2Cl3N trichloroacetonitrile 108-77-0 C2Cl4 tetrachloroethylene 127-18-4 C2Cl4O trichloroacetyl chloride 76-02-8 C2Cl4O2
List of compounds with carbon number 2
List_of_compounds_with_carbon_number_2
Pharmaceutical compound
PMC 1481817. PMID 13651584. Speeter ME, Anthony WC (1954). "The Action of Oxalyl Chloride on Indoles: A New Approach to Tryptamines". Journal of the American
N-Propyltryptamine
Psychedelic drug
procedure. First, 4-hydroxyindole is Friedel-Crafts-acylated with oxalyl chloride in position 3. The compound is further reacted with dimethylamine,
Psilocin
Chemical compound
1968. It was obtained by reacting tetrahydroxy-1,4-benzoquinone with oxalyl chloride in tetrahydrofuran. It is a yellow solid that can be crystallized as
Tetrahydroxy-1,4-benzoquinone bisoxalate
Tetrahydroxy-1,4-benzoquinone_bisoxalate
Pharmaceutical compound
analogues have been synthesized from 4-methylthio-indole, via the oxalyl chloride method and reaction with the appropriate amine. With dimethylamine
4-MeS-DMT
Chemical compound
synthesized by reacting 2-carbopentoxy-3,5,6-trichlorophenol with oxalyl chloride. When mixed with hydrogen peroxide in an organic solvent (diethyl phthalate
Bis(2,4,5-trichloro-6-(pentyloxycarbonyl)phenyl)oxalate
Bis(2,4,5-trichloro-6-(pentyloxycarbonyl)phenyl)oxalate
Surname list
formation of oxindoles by combining anilines and α-haloacid chlorides (or oxalyl chloride) Stol (disambiguation) Stole (disambiguation) Stoll (disambiguation)
Stolle
formed by the reaction of hydrogen peroxide with oxalate diesters or oxalyl chloride, with or without a base, although the reaction is faster with base
Peroxyoxalate
Chemical compound
(S=CS2(CH2)2). Oxalyl chloride gives oxalyl trithiocarbonate (S=CS2(C=O)2). Some of the organic trithiocarbonates Ethylene trithiocarbonate Oxalyl trithiocarbonate
Thiocarbonic_acid
Area of research analysing the modification of carbon nanotubes
The carboxylic group is converted into an acyl chloride with the use of thionyl or oxalyl chloride which is then reacted with the desired amide, amine
Carbon_nanotube_chemistry
Organic compound containing the cyclic group >CN2
iodine and triethylamine, oxidation by silver oxide, oxidation by oxalyl chloride, or even electrochemical oxidation on a platinum-titanium anode. Diazirines
Diazirine
Chemical compound
and a wide variety of electrophilic chlorinators, including oxalyl chloride, thionyl chloride, and phosphorus pentachloride, effect 3,3‑dichloro-1,2‑diphenylcyclopropene
Diphenylcyclopropenone
Chemical compound
hallucinogenic effects in humans. Speeter ME, Anthony WC (1954). "The Action of Oxalyl Chloride on Indoles: A New Approach to Tryptamines". Journal of the American
Dipropyltryptamine
Chemical compound
phenylacetic acid is treated with oxalyl chloride at room temperature to obtain 6-chloro-2,2-diphenylacetyl chloride 4. No purification is needed to start
Chlorophacinone
Chemical compound
solution of 2,4,6-trichlorophenol in dry toluene by reaction with oxalyl chloride in the presence of a base such as triethylamine. This method produces
TCPO
Chemical compound
hydrolyzes the latter back to the free acid, giving (2). Halogenation with oxalyl chloride and a Schotten–Baumann reaction with tert-butylamine yields the amide
Epristeride
Group of chemical compounds
chlorine, bromine and iodine. They include carbonyl halides, COX2, and oxalyl halides, C2X2O2, where X = F, Cl, Br or I. The halogen atoms X do not have
Carbon_oxohalide
Chemical compound
hydrolyzed in the alkaline to gem-diacid, halogenated with oxalyl chloride to gem-diacid chloride, with sodium azide transferred to the gem-diacid azide finally
Diethyl_oxomalonate
Chemical compound
side reaction in the production of allyl radicals from propene and oxalyl chloride. As a reaction intermediate, it is produced from electrocyclic ring-opening
1,3-Butadienal
calcium hydride) was stirred at 0 °C (ice bath) under nitrogen while oxalyl chloride (1.35 ml, 2.0 g, 15.75 mmol) was added dropwise. The ice bath was removed
Intramolecular reactions of diazocarbonyl compounds
Intramolecular_reactions_of_diazocarbonyl_compounds
Chemical compound
carcinogen. MCPO is synthesized by reacting methyl salicylate with oxalyl chloride in a solution of THF and pyridine: Pyridine reacts with HCl produced
MCPO
Organic chemistry
reaction or by the reaction of N-(benzyloxycarbonyl)-amino acids with oxalyl chloride. In the latter case, again the procedure is less efficient in the sense
Bailey_peptide_synthesis
Chemical group (–C(O)C≡N)
to cyanide (−C≡N). Examples include acetyl cyanide, formyl cyanide, and oxalyl dicyanide. Acyl cyanides are reagents in organic synthesis. Classically
Acyl_cyanide
Chemical compound
acyl chlorides from carboxylic acids using oxalyl or thionyl chloride. The catalytic mechanism entails reversible formation of an imidoyl chloride (also
Dimethylformamide
Chemical compound
basic catalyst. An improved procedure involves dehydrogenation with oxalyl chloride. Like all diazo compounds, diazodiphenylmethane is an alkylating agent
Diazodiphenylmethane
Chemical compound
carbon dioxide and hydrogen chloride which was possibly from the further decomposition of the intermediate oxalyl chloride. Tetrachloroethylene oxide (PCEO)
Tetrachloroethylene_oxide
several hours Trifluoromethylsulfinyl chloride CF3S(O)Cl Nitrosyl cyanide ?−20° blue-green gas 4343-68-4 Thiazyl chloride NSCl greenish yellow gas; trimerises
List_of_gases
Chemical compound
diphenylamine (1) and oxalyl chloride [79-37-8] gives intermediate, CID:11594101 (2). Haworth type intramolecular cyclization of the acid chloride occurs on heating
Linopirdine
Chemical synthesis of nucleic acids
086. Alul, R. H.; Singman, C. N.; Zhang, G.; Letsinger, R. L. (1991). "Oxalyl-CPG: a labile support for synthesis of sensitive oligonucleotide derivatives"
Oligonucleotide_synthesis
tetracarbide 12151-79-0 C4ClF7O heptafluorobutyryl chloride 375-16-6 C4Cl2F4O2 tetrafluorosuccinyl chloride 356-15-0 C4Cl2F4O3 chlorodifluoroacetic anhydride
List of compounds with carbon number 4
List_of_compounds_with_carbon_number_4
OXALYL CHLORIDE
OXALYL CHLORIDE
Female
Spanish
 Feminine variant spelling of Spanish unisex Odalis, ODALYS means "wealthy."
Surname or Lastname
English (West Midlands)
English (West Midlands) : habitational name from some minor locality, probably the lost Foxhale near Claverley, Shropshire, the name of which is derived from Old English fox ‘fox’ + halh ‘hollow’, ‘recess’. It is less likely that the surname is derived from Foxhall in Suffolk (earlier Foxhole), which is named from Old English fox + hol(h) ‘hollow’, ‘depression’: the surname is not established in East Anglia.
Boy/Male
German, Greek
Rich; Song
OXALYL CHLORIDE
OXALYL CHLORIDE
OXALYL CHLORIDE
OXALYL CHLORIDE
OXALYL CHLORIDE
OXALYL CHLORIDE
OXALYL CHLORIDE
n.
A genus of plants, mostly herbs, with acid-tasting trifoliolate or multifoliolate leaves; -- called also wood sorrel.
adv.
In an oral manner.
n.
An old name for carbonyl.
adv.
In a verbal manner; orally.
n.
A complex nitrogenous substance C3N3H5O3 obtained from alloxan (or when urea is fused with ethyl oxamate), as a stable white crystalline powder; -- called also oxaluramide.
n.
Same as Oxalan.
adv.
In an oval form.
a.
Pertaining to, derived from, or contained in, sorrel, or oxalis; specifically, designating an acid found in, and characteristic of, oxalis, and also certain plant of the Buckwheat family.
adv.
By, with, or in, the mouth; as, to receive the sacrament orally.
a.
Pertaining to, or designating, a nitrogenous acid which is obtained by the oxidation of uric acid, as a white crystalline substance (C3N2H2O3); -- also called oxalyl urea.
a.
Pertaining to, or designating, an aldehyde acid, intermediate between glycol and oxalic acid.
n.
The gadfly of cattle.
a.
Made or derived from oxalic acid; as, desoxalic acid.
v. i.
To plead orally; to argue a matter in court; to recite a count.
n.
An old name for carboxyl.
adv.
In a vocal manner; with voice; orally; with audible sound.
n.
Any one of three metameric radicals which are characteristic respectively of the three xylenes.
n.
A hydrocarbon radical (C2O2) regarded as a residue of oxalic acid and occurring in derivatives of it.
n.
A salt of oxalic acid.
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