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Chemical compound
Terpyridine (2,2';6',2"-terpyridine, often abbreviated to Terpy or Tpy) is a heterocyclic compound derived from pyridine. It is a white solid that is
Terpyridine
Chemical compound
(Terpyridine)ruthenium trichloride is the coordination complex with the formula RuCl3(terpy), where terpy is terpyridine. It is a brown paramagnetic solid
(Terpyridine)ruthenium trichloride
(Terpyridine)ruthenium_trichloride
Chemical reaction between identical molecules to produce ions
compounds of the type FeX2(terpyridine) (where X = Cl or Br) are unstable with respect to autoionization forming [Fe(terpyridine)2]2+[FeX4]2−. Ionization
Molecular_autoionization
2'- and 4,4'-2,2'-bipyridine. Complexes derived from the trioxide of terpyridine have been crystallized as well. Pyridine-N-oxides bind to metals through
Transition metal complexes of pyridine-N-oxides and amine oxides
Transition_metal_complexes_of_pyridine-N-oxides_and_amine_oxides
Chemical compound
Doxylamine. 2-Acetyl-1-pyrroline 6-Acetyl-2,3,4,5-tetrahydropyridine Terpyridine Sigma Adrich ChemicalBook National Toxicology Program"Summary of Data
2-Acetylpyridine
Chemical compound
occur in plants. ortho-Terphenyl meta-Terphenyl para-Terphenyl Biphenyl Terpyridine Terthiophene Triphenylene OMRE, experimental organic nuclear reactor
Terphenyl
Taiwanese politician
2': 6',2""-Terpyridine) with alkyl/aryl/allyl bromides and activated olefins in nonaqueous solvents", on the chemical compound Terpyridine. In college
Wang_Shih-chien
Chemical element with atomic number 44 (Ru)
often exist for both Ru(II) and Ru(III). Derivatives of bipyridine and terpyridine are numerous, best known being the luminescent tris(bipyridine)ruthenium(II)
Ruthenium
Method to separate compounds or metal complexes
americium by a combination of terpyridine and a carboxylic acid in tert-butyl benzene. In this case DAm = k [terpyridine]1[carboxylic acid]3[H+]−3 Another
Liquid–liquid_extraction
Chemical compound
compounds Related compounds 2,2′-Bipyridine Pyridine 4-Pyridylnicotinamide Terpyridine Biphenyl Except where otherwise noted, data are given for materials in
4,4'-Bipyridine
Insertion of molecules between DNA
iridium(III). Typical ligands attached to the metal ion are dipyridine and terpyridine whose planar structure is ideal for intercalation. Base pairs in DNA
Intercalation_(biochemistry)
ligands, such as 2,2'-bipyridine, 1,10-phenanthroline, or 2,2';6'2"-terpyridine. Polypyridines are multidentate ligands that confer characteristic properties
Polypyridine_complex
Chemical compound
compounds 4,4′-Bipyridine Pyridine Phenanthroline 3-Pyridylnicotinamide Terpyridine Biphenyl Except where otherwise noted, data are given for materials in
2,2′-Bipyridine
Ion or molecule bound to a metal atom
Sulfite O−SO2− 2 S−O2− 3 monoanionic monodentate ambidentate 2,2';6',2″-Terpyridine (terpy) NC5H4−C5H3N−C5H4N neutral tridentate meridional bonding only
Ligand
Number of atoms in a ligand that bond to the central atom of a coordination complex
ethylenediamine. Tridentate ligands bind with three atoms, an example being terpyridine. Tridentate ligands usually bind via two kinds of connectivity, called
Denticity
Metal chemical compound with all ligands identical
dimethylmercury Diethylzinc triethylborane Chromate Permanganate Ferroin bis(terpyridine)iron(II) IUPAC, Compendium of Chemical Terminology, 5th ed. (the "Gold
Homoleptic and heteroleptic compounds
Homoleptic_and_heteroleptic_compounds
Chemical compound
elucidated until 1956, when it was determined that nicotelline is a terpyridine consisting of three linked pyridine rings. This structure was confirmed
Nicotelline
American inorganic chemist
Oxidative Quenching of Electronically Excited Ru(tpy) (tpy = 2,2':6,2' '-terpyridine) by Ferric Ions in Aqueous Glasses at 77 K" (PDF). Journal of the American
Harry_B._Gray
Branch of chemistry
simple hydrogen bonding interactions. The complexation of bipyridines or terpyridines with ruthenium, silver or other metal ions is of great utility in the
Supramolecular_chemistry
Organised layer of amphiphilic molecules
U.; Landfester, K.; Behm, R.J. (2007). "Structure Formation in Bis(terpyridine)Derivative Adlayers – Molecule-Substrate vs. Molecule-Molecule Interactions"
Self-assembled_monolayer
Chemical reaction
4’-aryl-2,2’:6’, 2’’-terpyridines. Reaction of aryl aldehyde 26 with two equivalents of 2-acetylpyridine (27) yielded terpyridines of the form 28. In addition
Kröhnke_pyridine_synthesis
Cross coupling reaction in organic chemistry
all observations. Examination by Vicic and coworkers using tridentate terpyridine ligand identified intermediates of a Ni(II)-Ni(I)-Ni(III) catalytic cycle
Kumada_coupling
Class of enzymes
"Human thioredoxin reductase is efficiently inhibited by (2,2':6',2' '-terpyridine)platinum(II) complexes. Possible implications for a novel antitumor strategy"
Thioredoxin_reductase
Topics referred to by the same term
railway station in Turin, Italy tpy, abbreviation for the chemical ligand terpyridine This disambiguation page lists articles associated with the title TPY
TPY
Type of thin-film solar cell
that had much wider frequency response, notably "triscarboxy-ruthenium terpyridine" [Ru(4,4',4"-(COOH)3-terpy)(NCS)3], which is efficient right into the
Dye-sensitized_solar_cell
Sakamoto, R.; Katagiri, S.; Maeda, H.; Nishihara, H. (2013). "Bis (terpyridine) metal complex wires: Excellent long-range electron transfer ability
Hiroshi_Nishihara
Chemical compound
block for the organic semi-conductor polythiophene. Biphenyl Terphenyl Terpyridine "2,2':5',2"-Terthiophene". pubchem.ncbi.nlm.nih.gov. Smeets, B. J. J
Terthiophene
American chemist
demonstration to show a metal complex binding to DNA by intercalation: platinum terpyridine complexes inserted between the DNA base pairs and unwound the double
Stephen_J._Lippard
Italian chemist (born 1936)
Sauvage; V. Balzani; et al. (1994). "Ruthenium(II) and Osmium(II) Bis(terpyridine) Complexes in Covalently-Linked Multicomponent Systems: Synthesis, Electrochemical
Vincenzo_Balzani
Chemical compounds
nitrogen atom. Lutetium(III) nitrate can be crystallized with 2,2':6',2"-terpyridine (terpy) in dry acetonitrile to obtain colorless [Lu(terpy)(NO3)3], in
Lutetium_compounds
Chemical compound
triflate depicted below which is a benzotriyne synthon. Biphenyl Triphenyl Terpyridine Terthiophene Naphthalene where the rings are fused Tricyclobutabenzene
Tricyclobutabenzene
Chemical compounds containing ruthenium
often exist for both Ru(II) and Ru(III). Derivatives of bipyridine and terpyridine are numerous, best known being the luminescent tris(bipyridine)ruthenium(II)
Ruthenium_compounds
Class of chemical compounds
(2014-03-10). "Box-like Heterometallic Macrocycles Derived from Bis-Terpyridine Metalloligands". Organometallics. 33 (5): 1283–1290. doi:10.1021/om500093p
Nitrate_chlorides
contiguous, coplanar coordination sites. The most famous such ligand is terpyridine ("terpy"). Terpy and its relatives lack the steric bulk of the two terminal
Transition metal pincer complex
Transition_metal_pincer_complex
Chemical compounds containing zinc
ligands which have specific stereochemical requirements. For example, terpyridine, which is a tridentate ligand forms the complex [Zn(terpy)Cl2]. Another
Zinc_compounds
Type of chemical synthesis
main-chain supramolecular coordination polymers, reacting bis(2,2′:6′,2″-terpyridine)-functionalized poly(ethylene oxide) with various metal(II) acetates
Automated_synthesis
Index of chemical compounds with the same molecular formula
The molecular formula C15H11N3 may refer to: Nicotelline Terpyridine This set index page lists chemical structure articles associated with the same molecular
C15H11N3
catalyze the oxidation of water. Most catalysts feature bipyridine and terpyridine ligands. Catalysts containing pyridine-2-carboxylate exhibit rates (300
Water_oxidation_catalysis
Protein-coding gene in the species Homo sapiens
"Discovery of 5-chloro-N-[(5,6-dimethoxypyridin-2-yl)methyl]-2,2':5',3-terpyridine-3'-carboxamide (MK-1064): a selective orexin 2 receptor antagonist (2-SORA)
Hypocretin (orexin) receptor 2
Hypocretin_(orexin)_receptor_2
Russian chemist
development of several important organic chemical reactions. One is a novel terpyridine synthesis, the Chichibabin pyridine synthesis. The other reactions are
Aleksei_Chichibabin
Chemical compound
because it is a potential tetradentate ligand in coordination chemistry. terpyridine Nemertelline - isomer of quaterpyridine Gorczyński, Adam; Harrowfield
Quaterpyridine
Class of chemical compounds of nickel
nickel(II) triclinic 8.157 9.685 11.714 α=76.73 β=73.56 γ=78.23 854.2 2 aqua terpyridine(N,N´,N´´) thiosulfato(S,O) nickel(II) hemihydrate monoclinic,C2/c 27
Nickel_oxyacid_salts
British-American chemist (born 1948)
2 O)Mn III (O) 2 Mn IV (OH 2 )(terpy)](NO 3 ) 3 (terpy = 2,2':6,2' '-Terpyridine)". Journal of the American Chemical Society. 123 (3): 423–430. Bibcode:2001JAChS
Robert_H._Crabtree
Class of chemical compounds
949 b=16.783 c=11.649 β=105.208° hexakis(μ2-Selenido)-bis(2,2';6',2''-terpyridine)-di-manganese(ii)-di-tin {Mn(terpy)}2(μ-Sn2Se6) triclinic P1 a=9.430
Selenidostannate
Chemical compound
monoiodide reacts with multidentate Lewis bases, such as bipyridine, phenyl-terpyridine, and bis(imino)pyridine ligands to form Ga(III) complexes. Crystallographically
Gallium_monoiodide
Organophosphorus compound
and van der Est, Art. (2016). “Phosphorus(V) Porphyrin-Manganese(II) Terpyridine Conjugates: Synthesis, Spectroscopy, and Photo-Oxidation Studies on a
Phosphorus_porphyrin
Supermolecular coordination-based assembly methodology
extended structure was successfully obtained by appending secondary terpyridine groups onto the hemilabile ligands within the WLA subunits and allowing
Weak-Link_Approach
Fe2(CO)6(l-ADT) (ADT = azadithiolate) clusters bearing pendant 2,20:60,200-terpyridine domains and containing alkynylthienylene or alkynylphenylene spacers"
Hydrogenase_mimic
Chemical compound
"Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes". Dalton
Trimethylplatinum_iodide
TERPYRIDINE
TERPYRIDINE
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