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Type of compound
Phosphinidenes (IUPAC: phosphanylidenes, formerly phosphinediyls) are low-valent phosphorus compounds analogous to carbenes and nitrenes, having the general
Phosphinidene
4-coordinate silicon, which can also be viewed as silylene-stabilized phosphinidene, can be synthesized based on the reactivities of stable silyene complexes
Phosphasilene
Chemical compound
Wolczanski, Peter T.; Lobkovsky, Emil B. (1994-11-01). "Arsinidene, Phosphinidene, and Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E
Tris(silox)tantalum
Chemical compound
phosphanido, or dihydridophosphato(1−). A related substance has PH2−. Phosphinidene (PH) has phosphorus in a −1 oxidation state. As a ligand PH2 can either
Phosphanide
reacting with main-group starting materials such as ylides, silylene, and phosphinidene to synthesize and isolate for further steps. As CO becomes a more common
Ketenyl_anion
Chemical compound
monomeric intermediate fragment. The V-NP fragment undergoes singlet phosphinidene reactivity ([2+1] additions) with alkene and alkyne trapping agents
Phosphorus_mononitride
Molecular entity formed as an elementary step in a multi-step chemical reaction
Carbenoid Ion-neutral complex Keto anions Nitrenes Oxocarbenium ions Phosphinidenes Phosphoryl nitride Tetrahedral intermediates in carbonyl addition reactions
Reaction_intermediate
recent synthesis reported in 2019 proceeds through the transfer of a phosphinidene species from dibenzo-7-(R)-7-phospha-norbornadiene (RPA) onto styrene
Phosphiranes
Chemist
Massachusetts Institute of Technology Harvard University Thomas J. Watson Research Center Thesis Studies of terminal phosphinidene complexes of zirconium (1996)
Tricia_Carmichael
Type of chemical reaction
readily in cycloaddition reactions. Cycloaddition reactions of Ruthenium phosphinidenes with alkenes and alkynes is an active area research and has promise
Metal-centered cycloaddition reactions
Metal-centered_cycloaddition_reactions
American chemist
chemistry; especially their use in stabilizing carbenes, nitrenes, phosphinidenes, radicals and biradicals, 1,3-dipoles, anti-aromatic heterocycles, and
Guy_Bertrand_(chemist)
American chemist
University of Chicago Thesis The chemistry of three-coordinate nickel phosphinidene, imido, and carbene complexes (2004) Doctoral advisor Gregory L. Hillhouse
Rory_Waterman_(chemist)
Bertrand (born 1952) French chemist working on carbenes, nitrenes, phosphinidenes, radicals and biradicals Jöns Jakob Berzelius (1779–1848), Swedish chemist
List_of_chemists
Study of magnesium compounds in chemistry
give dibenzo-7λ3-phosphanorbornadiene (RPC14H10), which can be used as phosphinidene transfer reagent. The first characterized N-heterocyclic carbene (NHC)
Organomagnesium_chemistry
Chemical compound
to give complexes and clusters. It is the precursor to the bridging phosphinidene ligand in certain clusters. 2 (C6H5)2MCl + C6H5PH2 + 3 (C2H5)3N → ((C6H5)2M)2PC6H5
Phenylphosphine
Class of positively-charged molecules
R2N+ (protonated nitrenes) phosphinidenium cations, R2P+ (protonated phosphinidene) mercurinium cations, R3Hg+ (protonated organomercury compounds; formed
Onium_ion
proceed via metal phosphido intermediates. Some however proceed by metal-phosphinidene intermediates, i.e. species with M=PR double bonds. One such example
Hydrophosphination
Chemical compound
Fischer; Andre Mitschler (1982). "Generation and Trapping of Terminal Phosphinidene Complexes. Synthesis and X-ray Crystal Structure of Stable Phosphirene
Phosphirene
British chemistry professor (born 1974)
"Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes". Angewandte Chemie. 53: 4484-4488. doi:10.1002/anie.201400798
Stephen_Liddle
American inorganic chemist
Daniel J.; Hillhouse, Gregory L. (2002). "Monomeric Phosphido and Phosphinidene Complexes of Nickel". Journal of the American Chemical Society. 124
Gregory_L._Hillhouse
Family of chemical compounds
higher C-P bond character, and therefore better π-backbonding from the phosphinidene to the CAAC ligands. By correlation to the TEPs for these complexes
Cyclic_alkyl_amino_carbenes
Chemical compound
Complexes and Electron-Donating Properties of N-Heterocyclic-Carbene–Phosphinidene Adducts". European Journal of Inorganic Chemistry. 2016 (23): 3704–3713
Pentacarbonyl(tetrahydrofuran)tungsten
Pentacarbonyl(tetrahydrofuran)tungsten
Group of carbenes
carbene analog (RN) is called a nitrene. The phosphorus analog is a phosphinidene. There are charged group 15 carbene analogs as well, most notably phosphenium
Carbene_analog
Power, Philip P. (October 1986). "Synthesis and characterization of the phosphinidene borate complexes [Li(Et2O)2PRB(Mes)2] and [Li(12-crown-4)2][RPB(Mes)2]
Group_13/15_multiple_bonds
Organophosphorus compound with a phosphorus–phosphorus double bond
conjugation caused the compounds to exhibit reactivity closer to a phosphinidene. Cyclic voltammetry and UV/Vis spectra indicate that boryl-substituted
Diphosphenes
Class of chemical compounds
Klaus; Meyer, H.-Jürgen (September 2011). "Phosphorus-Centered and Phosphinidene-Capped Tungsten Chloride Clusters". European Journal of Inorganic Chemistry
Phosphide_chloride
Divalent cations of phosphorus
electrophiles with [(η5-C5Me5)Fe(CO)2]−; spectroscopic evidence for a phosphinidene complex". Inorganic Chemistry. 23 (22): 3431–3433. doi:10.1021/ic00190a001
Phosphenium
Class of carbon compounds
(2013). "Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene–carbene adducts". Chemical Communications. 49 (30): 3140–3142. doi:10
Carbodicarbenes
American chemist
carbene•cadmium, and carbene•lithium adducts. Reactions of carbenes with phosphinidenes were also reported from Arduengo's laboratory in addition to insertion
Anthony_J._Arduengo
Chemical compound
synthesize free, uncomplexed phosphet-2-ones with high yield using a phosphinidene transfer agent derived from anthracene. The reactivity of the phosphet-2-ones
Phosphetene
Family of chemical compounds
Schneider, Sven (2019-03-06). "Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer". Angewandte Chemie. 131
Stable_phosphorus_radicals
"Reactions of Tri- tert -Butylphosphatetrahedrane as a Spring-Loaded Phosphinidene Synthon Featuring Nickel-Catalyzed Transfer to Unactivated Alkenes"
Pnictogen-substituted tetrahedranes
Pnictogen-substituted_tetrahedranes
NZ–American physicist/chemist
Rhett C.; Protasiewicz, John D. (2001). "Three Different Fates for Phosphinidenes Generated by Photocleavage of Phospha-Wittig Reagents ArPPMe3". Journal
Cather_Simpson
Class of organobismuth compounds
formation of sp hybrid orbitals. In contrast, for the lighter congeners phosphinidenes, their smaller phosphorus 3s-3p energy gap favors a triplet ground state
Bismuthinidene
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Tamil
Purvith | பà¯à®°à¯à®µà®¿à®¤
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American, Australian, British, Chinese, English, Finnish, French, German, Italian, Latin, Portuguese, Spanish
Divine Protection; God's Helmet; Divine Helmet
Surname or Lastname
English and French
English and French : nickname for a gambler or for someone considered fortunate or well favored, from Middle English, Old French fortune ‘chance’, ‘luck’. In some cases it may derive from the rare medieval personal name Fortune (Latin Fortunius).French (Fortuné) : from the personal name Fortuné, a vernacular form of the Late Latin personal name Fortunatus meaning ‘prosperous’, ‘happy’.Scottish : habitational name from a place in Lothian, probably so named from Old English fÅr ‘hog’, ‘pig’ + tÅ«n ‘settlement’, ‘enclosure’; John de Fortun was servant to the abbot of Kelso c. 1200.
Boy/Male
Indian, Punjabi, Sikh
Victory in Remembrance of God
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British, English
Lathe Worker
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Hindu
Three words heaven, Earth, Hell
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Tamil
Mind identifier
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Hindu, Indian
Rays from Lord Shiva
Female
English
Pet form of English Lily, LILITA means "lily."
Girl/Female
Indian, Kashmiri
Love
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