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PHOSPHANIDE

Phosphanide

Chemical compound

Phosphanides are chemicals containing the [PH2]− anion. This is also known as the phosphino anion or phosphido ligand. The IUPAC name can also be dihydridophosphate(1−)

Phosphanide

Azanide

Anion derived from deprotonation of ammonia

Ammonia Structure Molecular shape Bent Related compounds Other anions Phosphanide Arsinide Imide Nitride Nitridohydride Related isoelectronic water, fluoronium

Azanide

Methylphosphine

Chemical compound

condenses to a colorless liquid. It can be produced by methylation of phosphanide salts: KPH2 + MeI → MePH2 + KI The compound exhibits the properties characteristic

Methylphosphine

Phosphine

Chemical compound hydrogen phosphide

exchange proceeds via a phosphonium (PH+4) ion in acidic solutions and via phosphanide (PH−2) at high pH, with equilibrium constants Kb = 4×10−28 and Ka = 41

Phosphine

Sodium bis(trimethylsilyl)amide

Chemical compound

Structures of Sterically Congested Sodium and Cesium Silyl(fluorosilyl)phosphanide Aggregates and Structural Characterization of the Trimeric Sodium

Sodium bis(trimethylsilyl)amide

Sodium_bis(trimethylsilyl)amide

Polyatomic ion

Ion containing two or more atoms

phosphate HPO2−4 Hydrogen peroxymonophosphate HPO2−5 Protonated twice Phosphanide H2P− Phosphinate or hypophosphite H2PO−2 Hydrogen phosphite H2PO−3 Dihydrogen

Polyatomic ion

Polyatomic_ion

Alkali hydroxide

selenium analog of hydroxide Azanide, a nitrogen analog of hydroxide Phosphanide, a phosphorus analog of hydroxide and azanide Arsanide, an arsenic analog

Alkali hydroxide

Alkali_hydroxide

Arsinide

Chemical compound

compounds Related compounds Arsanylium AsH+2 Arsine AsH3 Azanide NH−2 Phosphanide PH−2 Except where otherwise noted, data are given for materials in their

Arsinide

Phosphetane

Chemical compound

through sequential phosphanide/phosphine displacement of 1,3-alkyl dihalides or sulfonate esters (OTf, OTs, OMs, etc.). The phosphanide source is commonly

Phosphetane

Diphosphagermylene

Class of compounds

(2010-05-17). "Germanium(II) and Tin(II) Complexes of a Sterically Demanding Phosphanide Ligand". Inorganic Chemistry. 49 (10): 4698–4707. doi:10.1021/ic1003534

Diphosphagermylene

Potassium phosphide

Chemical compound

structure of potassium phosphide (K3P) Names Other names Tripotassium;phosphanide Tripotassium;phosphorus(3-) Tripotassium phosphide Identifiers CAS Number

Potassium phosphide

Potassium_phosphide

Metal bis(trimethylsilyl)amides

Group of chemicals

Structures of Sterically Congested Sodium and Cesium Silyl(fluorosilyl)phosphanide Aggregates and Structural Characterization of the Trimeric Sodium

Metal bis(trimethylsilyl)amides

Metal_bis(trimethylsilyl)amides

Topics referred to by the same term

phph PH2, a postcode in Perth, Scotland, see PH postcode area PH2− the phosphanide ion in inorganic chemistry -PH2 the phosphanyl group in organic chemistry

Ph2

Transition metal phosphido complexes

phosphido is often a bridging ligand. The -PH2 ion or ligand is also called phosphanide or phosphido ligand. One can generate transition-metal phosphido complexes

Transition metal phosphido complexes

Transition_metal_phosphido_complexes

Phosphasilene

the scheme on the left, it is also possible to use pre-formed lithium phosphanides Ar'P(H)Li as both a phosphorus source and a base. However, the latter

Phosphasilene

Online names & meanings

Harwick

Surname or Lastname

English

Harwick

English : probably a variant of Horwick, a topographic or habitational name from Old English horh â€˜muddyâ€™ + wÄ«c â€˜outlying dairy farmâ€™.German : habitational name from a place so called near Coesfeld, Westphalia.