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Dithiolene metal complexes are complexes containing 1,2-dithiolene ligands. 1,2-Dithiolene ligands, a particular case of 1,2-dichalcogenolene species along
Metal_dithiolene_complex
form of dithiolene ligands, the parent member being (HC)2S2−2. Metal thiolate complexes are commonly prepared by reactions of metal complexes with thiols
Transition metal thiolate complex
Transition_metal_thiolate_complex
Metal complex with a central selenium atom
1,2-Diselenolene metal complexes are a class of coordination compounds homologous to 1,2-dithiolene metal complexes and formally deriving from ene-1,2-diselenolato
Diselenolene_metal_complexes
Gotthard; Feng, Xinliang (2017). "Immobilizing Molecular Metal Dithiolene–Diamine Complexes on 2D Metal–Organic Frameworks for Electrocatalytic H2 Production"
Conductive metal−organic frameworks
Conductive_metal−organic_frameworks
Eisenberg, Richard; Gray, Harry B. (2011-10-17). "Noninnocence in Metal Complexes: A Dithiolene Dawn". Inorganic Chemistry. 50 (20): 9741–9751. doi:10.1021/ic2011748
Metal-ligand_cooperativity
Metal complexes with liquid crystalline behavior
classes of such materials are based on substituted ferrocenes and dithiolene complexes; more recent work shows that alkoxystilbazoles have similar utility
Metallomesogen
Chemical compound
to the dithiete. It is used to prepare metal dithiolene complexes. It reacts with low valent metal complexes by oxidative addition: Ni(CO)4 + 2 (CF3)2C2S2
3,4-Bis(trifluoromethyl)-1,2-dithiete
3,4-Bis(trifluoromethyl)-1,2-dithiete
Chemical compound
Cl− Enedithiolates displace all four chloride ligands to give bis(dithiolene) complexes. Reduction gives colloidal platinum of potential interest for catalysis
Potassium tetrachloroplatinate
Potassium_tetrachloroplatinate
Chemical compound
is a "dithiolene", i.e. a chelating alkene-1,2-dithiolate. It is a prototypical non-innocent ligand in coordination chemistry. Several complexes are known
Sodium_maleonitriledithiolate
Ligand with unclear oxidation state
bis(stilbenedithiolate) ([Ni(S2C2Ph2)2]z). As all bis(1,2-dithiolene) complexes of nd8 metal ions, three oxidation states can be identified: z = −2, −1
Non-innocent_ligand
Chemical species with two electrons occupying degenerate molecular orbitals
be found in coordination chemistry, for example among bis(1,2-dithiolene) metal complexes. Diradicals are usually triplets. The phrases singlet and triplet
Diradical
American chemist (1919–2011)
metal-dithiolene complexes, methyl ethylene phosphate, mercury amides, (NO)2, crystalline hydrogen fluoride, Roussin's black salt, (PCF3)5, complexes
William_Lipscomb
Material property in which absorbing EM radiation increases electrical conductivity
near-IR photodetector based on neutral [M(R-dmet)2] bis(1,2-dithiolene) metal complexes". Inorganic Chemistry Communications. 10 (2): 191–194. doi:10
Photoconductivity
Chemical compound
intermediate. Metals and trivalent phosphorus derivatives insert into the ring/reduce the dithione tautomer to give metal dithiolene complexes. Unsubstituted
Dithiete
Protein family
four thiolate-like ligands provided by the two dithiolene cofactors, the molybdopterins. The dithiolene and cysteinyl/selenocysteinyl ligands are redox-innocent
Formate_dehydrogenase
Chemical compound
Alkene-1,2-dithiols are unstable, although metal complexes of alkene-1,2-dithiolates, called dithiolene complexes, are well known. Karlin, K. D.; Stiefel
Benzene-1,2-dithiol
Mo(VI)O center is reduced, yielding water. Studies on synthetic Mo bis-dithiolene complexes suggest that to be oxygen-transfer, electron transfer. Using S K-edge
DMSO_reductase
Heterocyclic ligand that can complex molybdenum to form a Mo-cofactor
known as dithiolenes. Some bacterial oxidoreductases use tungsten in a similar manner as molybdenum by using it in a tungsten-pterin complex, with molybdopterin
Molybdopterin
Molybdopterin Synthase Provides Evidence for the Mechanism of Dithiolene Formation in Metal-binding Pterins". Journal of Biological Chemistry. 276 (39):
Molybdopterin_synthase
1,2-diimine. 1,2-Diketimines are “non-innocent ligands”, akin to the dithiolenes. For example, acetylacetone (2,4-pentanedione) and a primary alkyl- or
Diimine
American inorganic chemist
"Carbene-Stabilized Disilicon-Transfer Agent: Synthesis of a Diatonic Silicon Tris(dithiolene) Complex", Angewandte Chemie, International Edition 2020, 59, 8864–8867. Wang
Gregory_H._Robinson
Drug used to killed microorganisms or stop their growth
Massimiliano (May 2017). "[Au(pyb-H)(mnt)]: A novel gold(III) 1,2-dithiolene cyclometalated complex with antimicrobial activity (pyb-H=C-deprotonated 2-benzylpyridine;
Antimicrobial
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METAL DITHIOLENE-COMPLEX
METAL DITHIOLENE-COMPLEX
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Petal
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Friendly, Friendship, Sweet
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Hindu, Indian
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METAL DITHIOLENE-COMPLEX
METAL DITHIOLENE-COMPLEX
METAL DITHIOLENE-COMPLEX
METAL DITHIOLENE-COMPLEX
METAL DITHIOLENE-COMPLEX
METAL DITHIOLENE-COMPLEX
METAL DITHIOLENE-COMPLEX
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