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DIMBOA

DIMBOA

Chemical compound

DIMBOA (2,4-dihydroxy-7-methoxy-1,4-benzoxazin-3-one) is a naturally occurring hydroxamic acid, a benzoxazinoid. DIMBOA is a powerful antibiotic, fungicide

DIMBOA

2,4-Dihydroxy-7-methoxy-2H-1,4-benzoxazin-3(4H)-one 2 -D-glucosyltransferase

Class of enzymes

DIBOA and DIMBOA as non-toxic glucosides. DIMBOA + UDP-glucose UDP UDP DIMBOA glucoside For example, the enzyme interconverts DIMBOA and the (2R)

2,4-Dihydroxy-7-methoxy-2H-1,4-benzoxazin-3(4H)-one 2 -D-glucosyltransferase

2,4-Dihydroxy-7-methoxy-2H-1,4-benzoxazin-3(4H)-one_2_-D-glucosyltransferase

Maize

Species of grass cultivated as a food crop

powerful antibiotic substance, 2,4-dihydroxy-7-methoxy-1,4-benzoxazin-3-one (DIMBOA), which provides a measure of protection against a wide range of pests.

Maize

4-Hydroxy-7-methoxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl glucoside beta-D-glucosidase

Class of enzymes

4-benzoxazin-2-yl glucoside beta-D-glucosidase (EC 3.2.1.182, DIMBOAGlc hydrolase, DIMBOA glucosidase) is an enzyme with systematic name (2R)-4-hydroxy-7-methoxy-3-oxo-3

4-Hydroxy-7-methoxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl glucoside beta-D-glucosidase

4-Hydroxy-7-methoxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl_glucoside_beta-D-glucosidase

2,4,7-trihydroxy-1,4-benzoxazin-3-one-glucoside 7-O-methyltransferase

Class of enzymes

biosynthesis of the protective and allelopathic glucoside of the benzoxazinoid, DIMBOA, e.g. from the family Poaceae (grasses). Jonczyk R, Schmidt H, Osterrieder

2,4,7-trihydroxy-1,4-benzoxazin-3-one-glucoside 7-O-methyltransferase

2,4,7-trihydroxy-1,4-benzoxazin-3-one-glucoside_7-O-methyltransferase

Rhopalosiphum maidis

Species of true bug

4-dihydroxy-7-methoxy-l,4-benzoxazin-3-one glucoside (DIMBOA-Glc), an abundant maize benzoxazinoid. Both increased DIMBOA-Glc synthesis and reduced conversion to 2-hydroxy-4

Rhopalosiphum maidis

Rhopalosiphum_maidis

Bx1 benzoxazin1

results suggest that bx1 is responsible for much of the natural variation in DIMBOA (a benzoxazinoid compound) synthesis (Butron et al. 2010). Genetic variation

Bx1 benzoxazin1

Bx1_benzoxazin1

European corn borer

Species of moth

borer. Immature corn shoots accumulate a powerful antibiotic substance, DIMBOA, that serves as a natural defense against a wide range of pests and is also

European corn borer

European_corn_borer

Plant defense against herbivory

Evolutionary mechanism

salivation, diarrhea, and irritation of the mouth. Benzoxazinoids, such as DIMBOA, are secondary defence metabolites characteristic of certain grasses (Poaceae)

Plant defense against herbivory

Plant_defense_against_herbivory

Indole-3-glycerol-phosphate lyase

Class of enzymes

WS (1997). "A deletion in an indole synthase gene is responsible for the DIMBOA-deficient phenotype of bxbx maize". Proc. Natl. Acad. Sci. U.S.A. 94 (24):

Indole-3-glycerol-phosphate lyase

Indole-3-glycerol-phosphate_lyase

C9H9NO5

Index of chemical compounds with the same molecular formula

The molecular formula C9H9NO5 (molar mass: 211.17 g/mol) may refer to: DIMBOA, or 2,4-dihydroxy-7-methoxy-1,4-benzoxazin-3-one Nitroapocynin Topaquinone

C9H9NO5

Jonathan Gershenzon

American biochemist (born 1955)

Gershenzon, J., Vassão, D.G. (2014). Reglucosylation of the benzoxazinoid DIMBOA with inversion of stereochemical configuration is a detoxification strategy

Jonathan Gershenzon

Jonathan_Gershenzon

3-hydroxyindolin-2-one monooxygenase

Class of enzymes

involved in the biosynthesis of protective and allelopathic compounds such as DIMBOA in some plants. Glawischnig E, Grün S, Frey M, Gierl A (March 1999). "Cytochrome

3-hydroxyindolin-2-one monooxygenase

3-hydroxyindolin-2-one_monooxygenase

Benzoxazinone biosynthesis

in the pathway and determines much of the natural variation in levels of DIMBOA in maize. The next steps in the pathway occur in the endoplasmic reticulum

Benzoxazinone biosynthesis

Benzoxazinone_biosynthesis

2-Hydroxy-1,4-benzoxazin-3-one monooxygenase

Class of enzymes

involved in the biosynthesis of protective and allelopathic compounds such as DIMBOA in some plants. Bailey BA, Larson RL (March 1991). "Maize microsomal benzoxazinone

2-Hydroxy-1,4-benzoxazin-3-one monooxygenase

2-Hydroxy-1,4-benzoxazin-3-one_monooxygenase

2,4-Dihydroxy-1,4-benzoxazin-3-one-glucoside dioxygenase

Class of enzymes

C, Frey M, Gierl A (March 2008). "Elucidation of the final reactions of DIMBOA-glucoside biosynthesis in maize: characterization of Bx6 and Bx7". Plant

2,4-Dihydroxy-1,4-benzoxazin-3-one-glucoside dioxygenase

2,4-Dihydroxy-1,4-benzoxazin-3-one-glucoside_dioxygenase