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Class of chemical compounds
A Criegee intermediate (also called a Criegee zwitterion or Criegee biradical) is a carbonyl oxide with two charge centers. These chemicals may react
Criegee_intermediate
Rearrangement reaction in organic chemistry
with the Baeyer-Villiger oxidation where the intermediate hydroxyperacid is called a Criegee intermediate. The per-acid forms a per-ester with the alcohol
Criegee_rearrangement
Organic reaction
attacks the carbon of the carbonyl group forming what is known as the Criegee intermediate. Through a concerted mechanism, one of the substituents on the ketone
Baeyer–Villiger_oxidation
Reaction in organic chemistry
The Criegee oxidation is a glycol cleavage reaction in which vicinal diols are oxidized to form ketones and aldehydes using lead tetraacetate. It is analogous
Criegee_oxidation
German chemist (1902–1975)
Rudolf Criegee (23 May 1902 — 7 November 1975) was a German organic chemist. Criegee was born on 23 May 1902 in Düsseldorf to a wealthy family. His father
Rudolf_Criegee
Cleavage of C=C, C≡C, or N=N bonds with ozone
reverts to its corresponding carbonyl oxide (also called the Criegee intermediate or Criegee zwitterion) and aldehyde or ketone (3) in a retro-1,3-dipolar
Ozonolysis
Chemical reaction
ketone group on the catalyst (intermediate 1). This forms the reactive intermediate number 2 species, the Criegee intermediate that can potentially lead to
Shi_epoxidation
American physicist
Earth's atmosphere. Her work focuses on the hydroxyl radical and Criegee intermediates. Lester graduated from William Allen High School in Allentown, Pennsylvania
Marsha_I._Lester
Polish-Taiwanese chemist
Witek HA, Lee YP, "Infrared absorption spectrum of the simplest Criegee intermediate CH2OO", Science 340, 174 (2013). In 2005, he obtained Young Faculty
Henryk_Witek
Chemical compound
first reported it 1899. The reaction is believed to proceed via a Criegee intermediate and demonstrates good regioselectivity and chemoselectivity for the
Trifluoroperacetic_acid
Chemical compound
Its formation is thought to be radical in nature, preceding via a Criegee intermediate. Microwave analysis has indicated C-H, C-O and O-O bond lengths of
Dioxirane
Italian atmospheric chemist
developed a method for the quantification of the highly reactive Criegee intermediates produced by ozonolysis reactions in the atmosphere and she studied
Chiara_Giorio
Taiwanese chemist
research team at National Chiao Tung University that discovered the Criegee intermediate CH2OO particle in 2013. Lee was a 2017 recipient of the Humboldt
Yuan-Pern_Lee
Combining multiple simulation methods
; Stanton, John F. (2015-06-04). "Stabilization of the Simplest Criegee Intermediate from the Reaction between Ozone and Ethylene: A High-Level Quantum
Quantum chemistry composite methods
Quantum_chemistry_composite_methods
Class of enzymes
substrate. The process involves the formation of a flavin-peroxide and Criegee intermediate. CHMO is a member of the Baeyer-Villiger monooxygenase (BVMO) family
Cyclohexanone_monooxygenase
Organic chemical reaction
Beckmann rearrangement Benzilic acid rearrangement Brook rearrangement Criegee rearrangement Curtius rearrangement Dowd–Beckwith ring expansion reaction
1,2-rearrangement
Industrial process
step is similar to the mechanisms of the Baeyer–Villiger oxidation and Criegee rearrangement reactions, and also the oxidation step of the hydroboration–oxidation
Cumene_process
Chemical reaction
the carbonyl reactant to form the cyclic ozonide, as usual for the Criegee intermediate in the ozonolysis of alkenes. If no carbonyl compound is used, the
Griesbaum_coozonolysis
Chemical compound
proposed as part of a decomposition reaction of acetaldehyde oxide, the Criegee intermediate during some ozonolysis reactions. The methyl group helps reduce the
Methyldioxirane
Type of organic chemistry oxidation
reaction and Criegee oxidation, respectively. The former is favored for aqueous solutions, the latter for nonaqueous solutions. Cyclic intermediate are invariably
Glycol_cleavage
Organic compounds of the form >C=O
acetoacetic ester synthesis). Acid-catalysed rearrangement of 1,2-diols, or Criegee oxidation of the same. Ketones that have at least one alpha-hydrogen, undergo
Ketone
Class of enzymes
is postulated that the reaction proceeds through either a dioxetane or Criegee mechanism (figures 4, 5). While iron is by far the most prevalent cofactor
Dioxygenase
Organic compounds of the form R–O–O–R′
Heinz G. O. Becker Organikum, Wiley-VCH, 2001, ISBN 3-527-29985-8, p. 323 Criegee, Rudolf; Müller, Gerhard (1956). "1.2-Dioxan". Chemische Berichte. 89 (2):
Organic_peroxides
Negatively-charged molecule made of oxygen and iodine
tetraacetate which reacts in a similar manner and is soluble in organic solvents (Criegee oxidation). Periodate cleavage is often utilized in molecular biochemistry
Periodate
Set of rules pertaining to pericyclic reactions
Symmetry". Angew. Chem. Int. Ed. 8 (11): 781–853. doi:10.1002/anie.196907811. Criegee, Rudolf; Noll, Klaus (1959). "Umsetzungen in der Reihe des 1.2.3
Woodward–Hoffmann_rules
Organic compounds of the form R2C=C(R)OOR
"Acid‐Mediated Formation of Radicals or Baeyer–Villiger Oxidation from Criegee Adducts". Angewandte Chemie International Edition. 54 (40): 11848–11851
Alkenyl_peroxides
German chemist (born 1968)
Distinguished Lecture in the Sciences University of Southern California 2024 Criegee Lectureship (Karlsruhe Institute of Technology) Source: List, Benjamin;
Benjamin_List
April 2020. Retrieved 11 November 2020. "Nomination Archive – Rudolf Criegee". NobelPrize.org. April 2020. Retrieved 11 November 2020. "Nomination Archive
List of nominees for the Nobel Prize in Chemistry
List_of_nominees_for_the_Nobel_Prize_in_Chemistry
CRIEGEE INTERMEDIATE
CRIEGEE INTERMEDIATE
Girl/Female
Arabic
Fragrance; Beautiful Scent
Girl/Female
Indian, Sanskrit
Intermediate Region
Surname or Lastname
English
English : occupational name for a town crier, one whose job was to make public announcements in a loud voice, from Middle English, Old French criere (a derivative of Old French crier ‘to cry aloud’, Latin quiritare).Americanized spelling of German Kreyer or the Swiss variant Kreier.
CRIEGEE INTERMEDIATE
CRIEGEE INTERMEDIATE
Surname or Lastname
English
English : from an agent derivative of Middle English wasch(en) ‘to wash’ (Old English wæscan), hence an occupational name for a laundryman, or for someone who washed raw wool before spinning. Various other occupations, too, involved washing processes and the name may relate to any of these. For example, it may have denoted a man who washed sheep; some tenants on the manor of Burpham, near Worthing, in Sussex (where the surname is found from an early date), had as part of their feudal service to wash the flocks of their master.Americanized spelling of the German cognate Wascher.
Girl/Female
Indian
The Goddess who is armed with a wheel
Female
English
English form of French Joëlle, JOELLE means "Jehovah is God" or "to whom Jehovah is God."
Girl/Female
Hindu, Indian
Gold
Girl/Female
Indian
Light, Honor
Boy/Male
Indian
Brilliant
Girl/Female
Assamese, Gujarati, Hindu, Indian, Kannada, Malayalam, Marathi, Sanskrit, Telugu
Soft Spoken
Male
English
English variant spelling of Visigothic Alaric, ALLARICK means "all-powerful; ruler of all."
Girl/Female
Tamil
One who lives in heart
Girl/Female
Hindu, Indian, Traditional
An Auspiou Sign Drawn in Front of Hindu Home
CRIEGEE INTERMEDIATE
CRIEGEE INTERMEDIATE
CRIEGEE INTERMEDIATE
CRIEGEE INTERMEDIATE
CRIEGEE INTERMEDIATE
n.
A line for hauling the reef cringle to the yard; -- also called reef earing.
v. t.
To pass, as the end of a pope, through any hole in a block, thimble, cleat, ringbolt, cringle, or the like.
adv.
In an intermediate manner; by way of intervention.
n.
One who cringes.
n.
One who cringes meanly; a fawner.
n.
See Cringle.
n.
The quality or characteristics of a flunky; readiness to cringe to those who are superior in wealth or position; toadyism.
v. i.
To cringe.
n.
A withe for fastening a gate.
imp. & p. p.
of Cringe
v. i.
To bend; to crouch; to cringe.
n.
Servile civility; fawning; a shrinking or bowing, as in fear or servility.
n.
A poisonous amido acid, C6H13NO2, separated by Brieger from decaying horseflesh. In physiological action, it is similar to curare.
v. i.
To fawn; to cringe; to be obsequious.
v. i.
To bend servilely; to stoop meanly; to fawn; to cringe.
p. pr. & vb. n.
of Cringe
n.
A servile cringe or bow; mean flattery; sycophancy.
v. t.
To contract; to draw together; to cause to shrink or wrinkle; to distort.
n.
An iron or pope thimble or grommet worked into or attached to the edges and corners of a sail; -- usually in the plural. The cringles are used for making fast the bowline bridles, earings, etc.
v. t.
To draw one's self together as in fear or servility; to bend or crouch with base humility; to wince; hence; to make court in a degrading manner; to fawn.