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Coordination polymerisation is a form of polymerization that is catalyzed by transition metal salts and complexes. Coordination polymerization started
Coordination_polymerization
Polymer consisting of repeating units of a coordination complex
A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands. More formally a coordination
Coordination_polymer
Polymerization mechanism
Chain-growth polymerization (AE) or chain-growth polymerisation (BE) is a polymerization technique where monomer molecules add onto the active site on
Chain-growth_polymerization
Polymerization process involving free radicals as repeating units
In polymer chemistry, radical polymerization (RP) is a method of polymerization by which a polymer forms by the successive addition of a radical to building
Radical_polymerization
Class of chemical substance
Metal–organic frameworks (MOFs) are a class of coordination polymers consisting of metal clusters, also known as secondary building units (SBUs), coordinated
Metal–organic_framework
Chemical compound
low-density PE. The former is produced by free-radical polymerization and the latter by coordination polymerization (e.g. Ziegler-Natta catalysis. LDPE is a thermoplastic
Low-density_polyethylene
Polymer
polymerization. In contrast, conventional low-density polyethylene (LDPE) is produced by free-radical polymerization. In coordination polymerization,
Linear low-density polyethylene
Linear_low-density_polyethylene
Chain-growth polymerization without the ability to terminate
In polymer chemistry, living polymerization is a form of chain growth polymerization where the ability of a growing polymer chain to terminate has been
Living_polymerization
Compound with a metal center bound to ligands
A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and
Coordination_complex
Japanese chemist
coordination chemistry, with a focus on organic–inorganic hybrid compounds and the chemical and physical properties of porous coordination polymers,
Susumu_Kitagawa
British and Australian chemist (born 1937)
Chemistry at the University of Melbourne. Robson specialises in coordination polymers, particularly metal-organic frameworks. He has been described as
Richard_Robson_(chemist)
Most common thermoplastic polymer
Although ethylene is very stable, it polymerizes readily upon contact with catalysts. Coordination polymerization is the most prevalent technology. Common
Polyethylene
Method of industrial polymerization
Solution polymerization is a method of industrial polymerization. In this procedure, a monomer is dissolved in a non-reactive solvent that contains a
Solution_polymerization
Polymerization after alignment of monomers by crystallisation
Topochemical polymerization is a polymerization method performed by monomers aligned in the crystal state. In this process, the monomers are crystallised
Topochemical_polymerization
Chemist (born 1965)
various coordination polymers and the work of Hoskins and Richard Robson in 1989 on a 3D coordination polymer structure. However, these early coordination polymers
Omar_M._Yaghi
Chemical compound
Copper(II) thiocyanate (or cupric thiocyanate) is a coordination polymer with formula Cu(SCN)2. It is a black solid which slowly decomposes in moist air
Copper(II)_thiocyanate
Engineering field studying polymer materials
petrochemical industry, polymerization, structure and characterization of polymers, properties of polymers, compounding and processing of polymers and description
Polymer_engineering
Movement of the active site on one growing polymer chain to another molecule
ring-opening polymerization, coordination polymerization, and cationic polymerization, as well as anionic polymerization. IUPAC definitions Chain transfer
Chain_transfer
Organic reaction involving the breakup and reassembly of alkene double bonds
dates back to 1955), a reaction then classified as a so-called coordination polymerization. According to the then proposed reaction mechanism a RTiX titanium
Olefin_metathesis
Chemical compound
Copper(I) thiocyanate (or cuprous thiocyanate) is a coordination polymer with formula CuSCN. It is an air-stable, white solid used as a precursor for the
Copper(I)_thiocyanate
Chemical compound
of [Fe(C2O4)3]3-. Fe2(C2O4)3(H2O)x are coordination polymers with varying degrees of hydration. The coordination complex with the formula [Fe(C2O4)3]3-
Ferric_oxalate
Catalyst for synthesis of polymers of 1-alkenes
Heterogeneous supported catalysts based on titanium compounds are used in polymerization reactions in combination with cocatalysts, organoaluminum compounds
Ziegler–Natta_catalyst
Type of double stranded polymer which resembles a ladder in structure
BBL polymer concentration. Some polysilicates are ladder polymers. One example is provided by the mineral tremolite. In the area of coordination chemistry
Ladder_polymer
Chemical compound
{Zn[S2CN(H)CH2CH2N(H)CS2]}n. Structurally, it is classified as a coordination polymer and a dithiocarbamate complex. This pale yellow solid is used as
Zineb
non-covalent polymerization in supramolecular chemistry is highly dependent on the interactions during the self-assembly process. The degree of polymerization depends
Two-dimensional_polymer
Chemical compound made of only carbon and nitrogen
acts as a tetradentate bridging ligand in the three-dimensional coordination polymer Cu(tn)(tcpd). azidotetrazolate - CN−7 or N3−CN4−. It forms salts
Carbon_nitride
Type of chain-growth polymerisation reaction involving cyclic olefins
In polymer chemistry, ring-opening metathesis polymerization (ROMP) is a type of chain-growth polymerization involving olefin metathesis. The reaction
Ring-opening metathesis polymerization
Ring-opening_metathesis_polymerization
Polymer matrix capable of ion conduction
known as solid polymer electrolyte or solvent-free polymer electrolyte) arises from coordination of an inorganic salt to the polymer matrix. Application
Polymer_electrolytes
Chemical compound
been described as a 2D coordination polymer. In comparison, lead(II) acetate trihydrate's structure is a 1D coordination polymer. In the trihydrate, the
Lead(II)_acetate
Chemical compound
called copper(II) carbonate hydroxide. It can be classified as a coordination polymer or a salt. It consists of copper(II) bonded to carbonate and hydroxide
Basic_copper_carbonate
Chemical compound
of the anionic trisoxalato coordination complex of iron(III). It is a precursor to iron oxides, diverse coordination polymers, and Prussian blue. The latter
Ferric_ammonium_oxalate
Very long-chain polyethylene with high impact strength
catalysts and high pressures of ethylene. Catalysis is effected by coordination polymerization, which involves metallocene (Kaminsky catalysts) or Ziegler-Natta
Ultra-high-molecular-weight polyethylene
Ultra-high-molecular-weight_polyethylene
Study of organic compounds containing metal(s)
prepared in 1706 by paint maker Johann Jacob Diesbach as the first coordination polymer and synthetic material containing a metal-carbon bond.) The abundant
Organometallic_chemistry
Chemical compound
Crystal structure determination of bismuth subgallate revealed it is a coordination polymer with the formula [Bi(C6H2(O)3COOH)(H2O)]n2nH2O. The phenolate oxygen
Bismuth_subgallate
Chemical compound
polycarboxylic acid, acotinic acid forms a variety of coordination complexes. One example is the coordination polymer [Zn3(C6H3O6)2(H2O)6]n. "Aconitic Acid - Compound
Aconitic_acid
American chemist
Pd) complexes for olefin coordination polymerization. They carry out their mechanistic investigation of the polymerization reactions primarily by low
Maurice_Brookhart
Lithium-ion battery using a polymer electrolyte
Hyun-Kon (May 2019). "Gel Polymer Electrolytes: Gel/Solid Polymer Electrolytes Characterized by In Situ Gelation or Polymerization for Electrochemical Energy
Lithium_polymer_battery
Type of chemical synthesis
emulsion polymerization were compared, which found that the products were comparable. While juxtaposed against free-radical polymerization, the application
Automated_synthesis
Chemical compound
Controlled polymerization techniques, such as RAFT and NMP can be used for the direct polymerization of MAA. In contrast, polymerization of acidic monomers
Poly(methacrylic_acid)
Chemical mechanism that makes C-C bonds
The Cossee–Arlman mechanism in polymer chemistry is the main pathway for the formation of C–C bonds in the polymerization of alkenes. The mechanism features
Cossee–Arlman_mechanism
Family of copper salts
metal. They are cuprate salts and coordination polymers. Their primary interest is as simple models of the polymeric cuprate(III) sheet anion, notionally
Alkali_metal_cuprates(III)
Topics referred to by the same term
supplementary information, in scientific publications; for example see coordination polymerization Edge Side Includes, a markup language Electronically stored information
ESI
Chemical compound
and concentrated) → AgNO3 + H2O + NO2 Solid silver nitrate is a coordination polymer. The structure of silver nitrate has been examined by X-ray crystallography
Silver_nitrate
Chemical compound
used in salt-free reductions. 4,4′-bipyridine forms a variety of coordination polymers. See: Anderson, Thomas (1868). "On the products of the destructive
4,4'-Bipyridine
Polymeric arrays of repeating units connected by non-covalent bonds
supramolecular polymerization, where the monomer nucleates only in an early stage of polymerization to generate "seeds" and becomes active for polymer chain elongation
Supramolecular_polymer
Antacid medication
of advanced electron crystallography techniques, to be a layered coordination polymer with the formula BiO(C7H5O3). In the structure, both the carboxylate
Bismuth_subsalicylate
Class of coordination compounds with cyanide ligands (coordinating via C)
often used as building blocks for more complex structures called coordination polymers, the best known example of which is Prussian blue, a common dyestuff
Cyanometalate
Chain polymerization involving cyclic monomers
polymer chemistry, ring-opening polymerization (ROP) is a form of chain-growth polymerization in which the terminus of a polymer chain attacks cyclic monomers
Ring-opening_polymerization
Chemical compound
compound is of interest to researchers but not of particular value. BiF5 is polymeric and consists of linear chains of trans-bridged corner sharing BiF6 octahedra
Bismuth_pentafluoride
Chemical compound
laboratory tests. Structurally, it is a coordination polymer with formula UO2(CH3CO2)2(H2O)·H2O. In the polymer, uranyl (UO22+) centers are bridged by
Uranyl_acetate
Chemical compound
to simulate the coordination of histidine to heme complexes. It can be deprotonated to make imidazolate-based coordination polymers. 2-Methylimidazole
2-Methylimidazole
Chemical compound
with glycine. According to X-ray crystallography, the solid is a coordination polymer with one water of crystallization per formula unit. Other zinc-glycinates
Zinc_glycinate
Chemical compound
crystallography, it is a coordination polymer consisting of a linear chain of alternating Mo and F atoms. Each Mo center is octahedral, the coordination sphere being
Molybdenum_oxytetrafluoride
Attractive interaction between two molecules
also in abiologic chemical systems, e.g. as in cases of coordination polymers and coordination networks such as metal-organic frameworks. Molecular binding
Molecular_binding
Relative conformational uniformity of repeating units in a macromolecule
polymerization, the next monomer to be inserted will have the same stereochemistry as the previous monomer, while in a syndioselective polymerization
Tacticity
Chemical test for the reducibility of a sugar
crystal structure of a novel tartrate copper(II) two-dimensional coordination polymer: {[Cu2(C4H4O6)2(H2O)2]·4H2O}∞. In: J. Coord. Chem. 58, 2005, S. 1133–1138
Fehling's_solution
Inorganic salt: MgCl2 and its hydrates
[N(CH2CH3)4]2[MgCl4]. The adduct MgCl2(TMEDA) is another. In the coordination polymer with the formula MgCl2(dioxane)2, Mg adopts an octahedral geometry
Magnesium_chloride
Chemical compound
geometry as indicated by electron diffraction. As a solid, VF5 forms a polymeric structure with fluoride-bridged octahedral vanadium centers. The formation
Vanadium_pentafluoride
Chemical compound
nitrate, α and β, are known. Both polymorphs are three-dimensional coordination polymer networks with infinite chains of copper(II) centers and nitrate groups
Copper(II)_nitrate
Ion or molecule bound to a metal atom
In coordination chemistry, a ligand is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The
Ligand
Chemical compound
including Co(CH3CO2)2·H2O and [Co(CH3CO2)2]5·0.5 H2O. These are coordination polymers: Cobalt acetate is a precursor to various oil drying agents, catalysts
Cobalt(II)_acetate
Elements with atomic numbers 57-70
Sankar; George, Sumod; Goldberg, Israel (1 January 2007). "Framework coordination polymers of tetra(4-carboxyphenyl)porphyrin and lanthanide ions in crystalline
Lanthanide
Chemical compound
bactericide, and in the manufacture of antiseptics. It forms a variety of coordination polymers, a property that exploits the bridging tendency of the cyanide ligand
Potassium_dicyanoargentate
Supramolecular structures held together other than by covalent bonds
clathrates to exhibit electron crystal. Hofmann clathrates are coordination polymers, with the formula Ni(CN)4·Ni(NH3)2(arene). These materials crystallize
Host–guest_chemistry
Toxic, waxy organic compound
"Enhanced circularly polarized luminescence of chiral Eu(III) coordination polymers with structural strain". Dalton Transactions. 52 (3): 796–805. doi:10
Camphor
Chemical compound
compound with the formula Co(SCN)2. The anhydrous compound is a coordination polymer with a layered structure. The trihydrate, Co(SCN)2(H2O)3, is a isothiocyanate
Cobalt(II)_thiocyanate
Type of chemical equilibrium
dioxane to such solutions, however, leads to precipitation of the coordination polymers MgX2(μ-dioxane)2, driving the equilibrium completely to the right
Schlenk_equilibrium
Chemical compound
Nickel(II) thiocyanate is a coordination polymer with formula Ni(SCN)2. It is a green-brown solid and its crystal structure was determined first in 1982
Nickel(II)_thiocyanate
Chemical compound
temperature-dependent molecular sieving by a flexible chain-like coordination polymer". Nature Communications. 15 (1): 2240. Bibcode:2024NatCo..15.2240X
Cyclohexene
Ethylene polymerization catalyst
A Kaminsky catalyst is a catalytic system for alkene polymerization. Kaminsky catalysts are based on metallocenes of group 4 transition metals (Ti, Zr
Kaminsky_catalyst
Chemical compound
and purification by sublimation. Solid trimethyltin hydroxide is a coordination polymer. It forms orthorhombic crystals. The room temperature crystal structure
Trimethyltin_hydroxide
Chemical compound
crystallizes from concentrated hydrochloric acid. The dihydrate is a coordination polymer. Each Fe center is coordinated to four doubly bridging chloride ligands
Iron(II)_chloride
Chemical substance
that it is the product of partial hydrolysis of a three-dimensional coordination polymer 3 ∞ [Au2(μ2-NH2)(μ3-NH)2]Cl. Upon detonation, it produces a purple
Fulminating_gold
Inorganic chemical compound
contrasting properties: the trichloride is a colored solid, being a coordination polymer, and is paramagnetic. When the reduction is conducted in THF solution
Titanium_tetrachloride
"Chromocene catalysts for ethylene polymerization: Scope of the polymerization". Journal of Polymer Science Part A-1: Polymer Chemistry. 10 (9): 2621–2637.
Organochromium_chemistry
Chemical compound
ethionamide and dexamethasone isonicotinate. Its conjugate base forms coordination polymers and MOFs by binding metal ions through both the N and carboxylate
Isonicotinic_acid
Chemical compound
also a Lewis base, binding Lewis acids at the C−N=N center. A variety coordination complexes are known such as the tetrahedral 2:1 derivative with zinc
Benzotriazole
Reversible-deactivation radical polymerization
Atom transfer radical polymerization (ATRP) is an example of a reversible-deactivation radical polymerization. Like its counterpart, ATRA, or atom transfer
Atom transfer radical polymerization
Atom_transfer_radical_polymerization
Chemical compound
Other reducing agents have been examined. The α form is a linear coordination polymer consisting of chains of octahedral uranium centers in which one of
Uranium_pentafluoride
Chemical compound
Vanadyl acetate is the coordination polymer with the empirical formula VO(CH3COO)2, which can be simplified to VO(OAc)2 and giving rise to a systematic
Vanadyl_acetate
Chemical compound
(dihydrate) Y[scifinder] 26935-72-8 (HMn3O(OAc)8 polymer) Y 993-02-2 (anhydrous) Y 3D model (JSmol) Interactive image coordination complex: Interactive image ChemSpider
Manganese(III)_acetate
Group of chemical compounds
structure, 4,4′-bipyridine can bridge between metal centres to give coordination polymers. The 3,4′-bipyridine derivatives inamrinone and milrinone are used
Bipyridine
Chemical compound
the metal centers adopt an octahedral coordination geometry, {PtCl6}. This geometry is achieved by forming a polymer wherein half of the chloride ligands
Platinum(IV)_chloride
Chemical compound
inorganic compound with the formula Pd(CN)2. A grey solid, it is a coordination polymer. It was the first palladium compound isolated in pure form. In his
Palladium_dicyanide
summarizes homoleptic transition metal azides, which are often coordination polymers. Azide is a pseudohalide but more nucleophilic than chloride, as
Transition metal azide complex
Transition_metal_azide_complex
Pigments developed in ancient China
with oxalic acid to form BaCu(C2O4)2. The light blue color of this coordination polymer may explain the light blue color of some of the Terracotta Warriors'
Han_purple_and_Han_blue
Chemical compound
under flowing hydrogen chloride. The dihydrate, CoCl2(H2O)2, is a coordination polymer. Each Co center is coordinated to four doubly bridging chloride ligands
Cobalt(II)_chloride
Chemical compound
According to X-ray crystallography, anhydrous lanthanum acetate is a coordination polymer. Each La(III) center is nine-coordinate, with two bidentate acetate
Lanthanum_acetate
Chemical compound
method of preparing such phosphine complexes is to break up the coordination polymer of palladium(II) chloride into reactive, monomeric acetonitrile or
Sodium_tetrachloropalladate
Class of chemical substance
Metal–organic nanotubes (MONTs) are a class of crystalline coordination polymers consisting of organic ligands bonded to a metal or metal cluster that
Metal-organic_nanotube
Chemical substance consisting of a cage-like host lattice containing guest species
hydroquinone clathrates. Hofmann clathrates are cyanometallate coordination polymers that include small aromatic guests. Na8Si46 is a type-I inorganic
Clathrate_compound
Chemical compound
are yellow diamagnetic solids. Solid forms of molybdic acid are coordination polymers. The monohydrate MoO3·H2O consists of layers of octahedrally coordinated
Molybdic_acid
Chemical compound
application but is used on a laboratory scale for the synthesis of coordination polymers. Its controlled decomposition to zinc oxide has also been used for
Zinc_nitrate
Class of chemical compounds
Transition metal carboxylate complexes are coordination complexes with carboxylate (RCO2−) ligands. Reflecting the diversity of carboxylic acids, the inventory
Transition metal carboxylate complex
Transition_metal_carboxylate_complex
Chemical compound
"Hexamethylenetetramine: An old new building block for design of coordination polymers". Coordination Chemistry Reviews. 255 (15–16). Elsevier BV: 1603–1622. doi:10
Hexamethylenetetramine
Material that responds to stimuli
repeating coordination entities in two or three dimensions. A coordination polymer is a coordination compound with repeating coordination entities extending
Flexible metal-organic framework
Flexible_metal-organic_framework
Chemical compound
All the other uranium fluorides are nonvolatile solids that are coordination polymers. The conversion factor for the 238U isotopologue of UF6 ("hex")
Uranium_hexafluoride
Chemical compound
Gerhard Erker (1990). "Mono(η-cyclopentadienyl)zirconium Complexes: from Coordination Chemistry to Enantioselective Catalysis". Journal of Organometallic Chemistry
(Cyclopentadienyl)zirconium trichloride
(Cyclopentadienyl)zirconium_trichloride
Chemical compound
2ZnO·3B2O3·7H2O 3ZnO·5B2O3·14H2O 4ZnO·B2O3·H2O 6ZnO·5B2O3·3H2O They are coordination polymers consisting of zinc(II) centers bonded to cyclic boron oxide rings
Zinc_borate
Chemical compound
+ H2O The anhydrous material and dihydrate Mn(CH3CO2)2·2H2O are coordination polymers. The dihydrate has been characterized by X-ray crystallography.
Manganese(II)_acetate
COORDINATION POLYMERIZATION
COORDINATION POLYMERIZATION
Boy/Male
Hindu
Co-coordinator
Boy/Male
Tamil
Samanvey | ஸமாஂநà¯à®µà¯‡à®¯Â
Coordination
Samanvey | ஸமாஂநà¯à®µà¯‡à®¯Â
Boy/Male
Tamil
Co-coordinator
Boy/Male
Hindu, Indian
Coordination
Boy/Male
Indian, Telugu
Coordinator; Conveyor; Become a Leader
COORDINATION POLYMERIZATION
COORDINATION POLYMERIZATION
Boy/Male
Arabic, Muslim
A Twinkle; Star in the Sky
Surname or Lastname
English
English : nickname from a diminutive of Middle English sparewe ‘sparrow’ (see Sparrow).Altered form of German Sperling.
Surname or Lastname
English
English : habitational name from a place in Buckinghamshire, so called from the Old English river name SÇ£ge, which probably meant ‘trickling’, ‘slow-moving’, + Old English brÅc ‘stream’.
Girl/Female
French
Wild rose.
Male
Spanish
Spanish form of Latin Rogerius, ROGERIO means "famous spear."Â
Surname or Lastname
English
English : occupational name for a refiner of gold and other metals, from Middle English fine(n) ‘to refine or purify’ (a derivative of fine ‘fine’, ‘pure’).Probably a translated form of German Feiner.
Girl/Female
Arabic, Muslim
Enchantment; Captivation
Boy/Male
Arabic
Prophet
Boy/Male
Gujarati, Hindu, Indian, Punjabi, Sikh
Parrot
Boy/Male
Celtic English
Hilltop.
COORDINATION POLYMERIZATION
COORDINATION POLYMERIZATION
COORDINATION POLYMERIZATION
COORDINATION POLYMERIZATION
COORDINATION POLYMERIZATION
n.
The ordination of a person to fill a station already occupied; especially, the ordination by an ecclesiastical official, during his lifetime, of his successor.
v. t.
To lay on, as the hands, in the religious rites of confirmation and ordination.
v. t.
To ordain again, as when the first ordination is considered defective.
n.
Any service other than that of ordination and the Mass; any prescribed religious service.
n.
Wrong ordination.
n.
Establishment in life, in business, condition, etc.; ordination or installation as pastor.
p. pr. & vb. n.
of Coordinate
a.
Expressing coordination.
n.
The act of setting apart to an office in the Christian ministry; the conferring of holy orders.
n.
The state of being coordinate, or of equal rank, dignity, power, etc.
n.
Ordination.
n.
Disposition; arrangement; order.
n.
A second ordination.
n.
Want of coordination; lack of harmonious adjustment or action.
n.
Disorder; dissoluteness.
n.
The act of laying on the hands as a religious ceremoy, in ordination, confirmation, etc.
n.
The act of coordinating; the act of putting in the same order, class, rank, dignity, etc.; as, the coordination of the executive, the legislative, and the judicial authority in forming a government; the act of regulating and combining so as to produce harmonious results; harmonious adjustment; as, a coordination of functions.
n.
Deviation from custom, rule, or right; irregularity; inordinacy.
n.
The act of ordaining, appointing, or setting apart; the state of being ordained, appointed, etc.
n.
Previous ordination or appointment; predetermination; predestination.