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Chemical compound
Barrelene is a bicyclic organic compound with chemical formula C8H8 and systematic name bicyclo[2.2.2]octa-2,5,7-triene. First synthesized and described
Barrelene
Photochemical reaction
moiety: This rearrangement was originally encountered in the photolysis of barrelene to give semibullvalene. Once the mechanism was recognized as general by
Di-π-methane_rearrangement
Organic molecule (C10H10)
replaced by a single bond. The compound was first prepared by photolysis of barrelene in isopentane with acetone as a photosensitizer in 1966. Semibullvalene
Bullvalene
Index of chemical compounds with the same molecular formula
The molecular formula C8H8 may refer to: Barrelene Benzocyclobutene (BCB) Cubane Cuneane Cyclooctatetraene Heptafulvene Octabisvalene Polystyrene, repeating
C8H8
Howard E.; Robert M. Paufler (1960). "Bicyclo [2.2.2]octa-2,5,7-triene (barrelene), a unique cyclic six electron pi system". Journal of the American Chemical
List of chemical compounds with unusual names
List_of_chemical_compounds_with_unusual_names
bridged bicyclo-octatriene core structure. They are formally derivatives of barrelene. The first and simplest iptycene molecule is triptycene. The first iptycene
Iptycene
Chemical compound
suffered from high toxicity. COT can also be prepared by photolysis of barrelene, one of its structural isomers, the reaction proceeding via another isolable
Cyclooctatetraene
Chemical compound
three-piece art panel, the triptych. Several substituted triptycenes are known. Barrelenes are structurally related. Due to the rigid framework and three-dimensional
Triptycene
Special type of aromaticity
\cos {\frac {2k\pi }{N}}\quad (k=0,1,\ldots ,\lfloor N/2\rfloor )} . Barrelene Baird's rule Bicycloaromaticity Rzepa, Henry S. (2005). "Möbius Aromaticity
Möbius_aromaticity
Chemical compound
L. A.; Cabeza, J. A. (1985). "Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I)". Inorganic Syntheses. Vol. 23
Cyclooctadiene iridium methoxide dimer
Cyclooctadiene_iridium_methoxide_dimer
Organic molecular structure
the best examples of neutral homoaromatics are bishomoaromatics such as barrelene and semibullvalene. First synthesized in 1966, semibullvalene has a structure
Homoaromaticity
Chemical compound
L. A.; Cabeza, J. A. (1985). "Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I)". Inorganic Syntheses. Vol. 23
Cyclooctadiene iridium chloride dimer
Cyclooctadiene_iridium_chloride_dimer
Chemical compound
Wagner, M. (2014). "Insertion Reactions into the Boron–Boron Bonds of Barrelene-Type 1,2-Diaminodiboranes(4)". Organometallics. 33 (23): 6967–6974. doi:10
Triethylphosphine
Nonsystematic name for a chemical substance
shape of the molecule. Some are pictured below. Other examples include barrelene (shaped like a barrel), fenestrane (having a window-pane motif), ladderane
Trivial_name
American academic
Mariano, P. S. J. Am. Chem. Soc., 1969, 91, 1718-1727. ISSN 0002-7863 "The Barrelene to Semibullvalene Transformation. Correlation of Excited State Potential
Howard_Zimmerman
3-dimethyl-1,4-pentadiene (the "Mariano" molecule) and the rearrangement of barrelene to semibullvalene. We note that, in contrast to the cyclohexadienone reactions
Organic_photochemistry
the Fields Medal in 1994 Howard Zimmerman, organic chemist, discovered barrelene Otto Julius Zobel, inventor of the m-derived filter and the Zobel network
List of University of Wisconsin–Madison people
List_of_University_of_Wisconsin–Madison_people
Molecule interconvertable with another through pericyclic reactions
least 21: Valence isomers of cyclooctatetraene Cyclooctatetraene (COT) Barrelene Cubane Cuneane Semibullvalene 1,5-dihydropentalene 2a,2b,4a
Valence_isomer
BARRELENE
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Girl/Female
Hindu, Indian, Marathi, Sanskrit
Gleaming; Sparkling
Girl/Female
English American
from Thracia.
Girl/Female
Biblical
The hand of slander, or of cursing.
Surname or Lastname
English
English : variant spelling of Langhorne.
Boy/Male
Sikh
One aware of elixir of naam
Girl/Female
German
Lure to the Rocks
Boy/Male
Russian
Little.
Boy/Male
British, English
Like the Wind
Girl/Female
American, Australian, British, English
Wide Meadow; From St Denis
Surname or Lastname
Danish and Norwegian
Danish and Norwegian : patronymic from the personal name Ivar, from Old Norse Ãvarr, a compound of either Ãv ‘yew tree’, ‘bow’ or Ing (the name of a god) + ar ‘warrior’ or ‘spear’.North German (Frisian) : patronymic from a Germanic personal name composed of the elements Ä«wa ‘yew (tree)’ + hard ‘strong’, ‘firm’.English : variant spelling of Iverson.
BARRELENE
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BARRELENE