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• SEGPHOS

Chemical compound

the bulkier derivatives DM-SEGPHOS and DTBM-SEGPHOS are also commercially available. In DM-SEGPHOS and DTBM-SEGPHOS, the phenyl groups of SEGPHOS are

SEGPHOS



SEGPHOS

• Tetrafluoroborate

Anion

between boron and the cationic center. For instance, the gold complex [μ-(DTBM-SEGPHOS)(Au−BF4)2] was found crystallographically to contain two Au−F−B bridges

Tetrafluoroborate



Tetrafluoroborate

• Hydrocupration

Chemical reaction

render the reaction enantioselective through the utility of a chiral ligand (DTBM-SEGPHOS). For unactivated (aliphatic alkenes), the group observed anti-markovnikov

Hydrocupration



Hydrocupration

• Organogold chemistry

Study of compounds containing gold–carbon bonds

to afford the cyclopropanation product. The use of a chiral ligand ((R)-DTBM-SEGPHOS) resulted in good to excellent levels of enantioselectivity. Chiral

Organogold chemistry

Organogold_chemistry

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