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  • Inverted ligand field theory
  • Frontier orbitals of mono-, di-, and trianionic [Cu(CF3)4]n- calculated with the B3LYP functional using a D3BJ def2-TZVP(-f) basis and visualised by IboView.

  • Basis set (chemistry)
  • polarization def2-SVPD – Split valence polarization with diffuse functions def2-TZVP – Valence triple-zeta polarization def2-TZVPD – Valence triple-zeta polarization

  • Ketenyl anion
  • bond orbitals of K[PPh2(=S)CCO] (CCDC-2201261), calculating by ORCA def2-TZVP basis set. The geometry of the structure was optimized by r2SCAN3c method

  • Dichlorotrimethyltantalum
  • quadruply degenerate HOMO of TaCl2Me3: a Ta-Cl pi bond. Kohn-Sham method (DFJX-RKS) with PBE functional and def2-TZVP basis. Image generated from IBOView

  • Phosphorus mononitride
  • of PN. Example calculated at the PBE0-D3BJ level of theory using the def2-TZVP basis set with ORCA. (Left): Two lone pairs + one P-N sigma bond. (Middle

  • Borole
  • to the right. Tholen et al. performed DFT calculations at the M06-2X/Def2-TZVP level of theory and determined that the model complex matched up closely

  • Dinitrogen complexes of main-group elements
  • Gibbs free energy of −74.5 kcal mol−1. Meanwhile, Wilson et al.’s MP2/TZVP//B3LYP/TZVP value was slightly larger in magnitude at −87.8 kcal mol−1, but in

  • Bis(cyclopentadienyl)titanium(III) chloride
  • The calculated spin density of the ground state singlet biradical (broken symmetry density functional theory, TPSSh/def2-TZVP).

  • Rosenthal's reagent
  • data. Further DFT calculations were carried out using the PBE0 D3BJ/ def2-TZVP functional and visualization in IBOview. These illustrate the nature of the

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Astrological/horoscope meaning of tzvp. tzvp means: With a Life Path 3, your numbers are (3, 12/3, 21,/3). The Life Path 3 shows you have a strong sense of creativity and wonderful communication skills. Your performance for most things comes through its ingenious expression. A truly gifted 3 has the extraordinary ability to innovate, usually in the verbal area, write, speak, act, or similar circumstances. They are great entertainers in the world, and their brightness sparkles with a very optimistic attitude. The positive side of this path stresses harmony, beauty and pleasure; their talents to share with the world of invention. The acquisition and capacity in creative self-expression is the highest level of performance for this type of life.Life path 3's live thier lives to fullest, often without much worry about tomorrow. They are not very good with money because of the general lack of concern in cautious spending. You spend it when you have it and not when you don't.3's like to connect with people. The characteristics of the 3 are warmth and friendliness, good conversationalist, social and open. A good speaker, both from the standpoint of being a joy to listen to, but more importantly, those who have to listen to other's ability. Thus the life path 3 persons are always a welcome addition to any social situation and always know how others feel at home. Their approach to life tends to be very positive. Their view is almost sunny, safe and open heart. They are happy and often inspired on the lookout for and need to stimulate and encourage others.There is a not so glamourous side the life path of 3 so to speak. This is a surprise for those who think they are well acquainted. 3 is actually a very sensitive soul. If injured, you can easily retreat into a shell of sullen silence for long periods. However, with the many setbacks that occur in life, they readily bounce back for more. It is usually easy for you to deal with the problems as they are free, the non-existence of problems can result in long periods of slow decline. You are very sensitive to the feelings, emotions and aspirations of others.In romance, 3 is a very passionate and faithful lover. Emotional experiences of all kinds deeply affect 3s in general and can take the form of drama in some cases. The emotional connection for 3s could be sometimes demanding to their partner or friends. As with most problems in life for life path 3 balance in relations is hard to achieve.The big test with a 3 Life path is in managing the ups and downs of life. They are not very well suited in any environment that requires routine or when placed under a dominant person. They are sometimes slow because they are contemplative in thought as they struggle to please people enough. This could sometimes be a frustrating affair when working with or among them.For the few to be on the negative side of this path of life, 3s live with the joy to feel impressed and be impressed. They may treat life frivolously and in a superficial way sometimes. It is possible to dispel their abilities and express little sense of concern. 3 may be a mystery, can be moody for no apparent reason and tend to withdraw. Escapist tendencies with the 3 life path is not unusual, and it is very difficult to stay in one place or position as they are grigarious and like to enjoy life. They hate to be critical to avoid negative energies, could be impatient, intolerant, or overly optimistic.

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    T: Meaning of T in the acronym tzvp means: T is a vertical strand crossed at the top by a horizontal strand. With the top strand balanced in the middle by the vertical strand, T shows balance and stability in its ways. It is also forgoing and spiritual. With the top strand projected up by the bottom strand, T is highly ambitious, but also kind to others as it can let others rest on its horizontal top. This makes T selfless, cooperative, womanly and dutiful. It also displays a high degree of generosity and liberalism.

    Z: Meaning of Z in the acronym tzvp means: The letter Z zigzags forward and backwards to explore both the left and right sides of the universe. It's bottom is flat showing a certain degree of stability. Z is determined and helpful. The lower and upper cases of Z look the same indicating Z is unchanging, highly esteemed, immense and compelling.

    V: Meaning of V in the acronym tzvp means: V sits on a single bottom end with to arms projecting upwards in a slanted way. It displays remarkable accessibility and its extensions show a desire to grasp. It is also authoritative and painstaking. It's shrewdness is seen in the fact that it converges it's energies at the bottom. It is therefore skilled or masterly in planning.

    P: Meaning of P in the acronym tzvp means: P has a heavy top standing on just a point to show it's strenght. It means strong, the ability tp perceive weakness and opportunities easily and clear-sightedness. By standing on its own, it shows self-centeredness, a thriving attitude and rigorousness. P also shows disconnection, strong will to go even alone and impartiality.

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