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  • Bridging ligand
  • dicarbonyl dimer: Co2(μ-CO)2(CO)6 ⇌ Co2(μ-CO)2(CO)4(CO)2 (C5H5)2Fe2(μ-CO)2(CO)2 ⇌ (C5H5)2Fe2(μ-CO)2(CO)2 These dynamic processes, which are degenerate, proceed

  • Half-reaction
  • example: Fe2+ → Fe3+ + e− becomes 2Fe2+ → 2Fe3+ + 2e− is added to Cl2 + 2e− → 2Cl− and finally becomes Cl2 + 2Fe2+ → 2Cl− + 2Fe3+ It is also possible

  • Chalcopyrite
  • 2CuFeS2 + 4Fe2(SO4)3 -> 2Cu2++ 2SO42- + 10FeSO4+4S ii) 4FeSO4 + O2 + 2H2SO4 -> 2Fe2(SO4)3 +2H2O iii) 2S + 3O2 +2H2O -> 2H2SO4 (overall) 4CuFeS2+ 17O2 + 4H2O

  • Ferredoxin
  • redox scheme: The formal oxidation numbers of the iron ions can be [2Fe3+, 2Fe2+] or [1Fe3+, 3Fe2+] in low-potential ferredoxins. The oxidation numbers of

  • Iron-sulfur protein
  • the following redox scheme: In HiPIP, the cluster shuttles between [2Fe3+, 2Fe2+] (Fe4S42+) and [3Fe3+, Fe2+] (Fe4S43+). The potentials for this redox couple

  • Standard electrode potential (data page)
  • PtCl2− 6 + 2 e− ⇌ PtCl2− 4 + 2Cl− 0.726 2 Fe Fe 2O 3(s) + 6 H+ + 2 e− ⇌ 2Fe2+ + 3H2O 0.728 2 : p.100  Se H 2SeO 3(aq) + 4 H+ + 4 e− ⇌ Se(s) + 3H2O 0.74

  • Flyover complex
  • Structure of an asymmetrical flyover complex (C5H5)2Fe2[(CCF3)4CO]CO. The Fe-Fe bond length is 258.8 picometers.

  • Silanide
  • 35 γ=72.79 Z=2 732.1 1.742 light yellow [(μ2-CO)Cp2(OC)2Fe2]SiH2 dark red [(μ2-CO)Cp2(OC)2Fe2][Cp(OC)2Fe]SiH dark red HNiSiH3 HZnSiH3 [(dtbpCbz)GeSiH3]2•C6H18

  • Dagetichthys
  • 1361359 ITIS: 616008 NCBI: 1740823 Open Tree of Life: 3640755 Plazi: 8766EF41-2FE2-2C96-7228-470980225748 WoRMS: 268943 ZooBank: 90FA566A-3FC8-4E46-BA9D-38AF095095F2

  • Iron(III) citrate
  • yielding carbon dioxide and acetonedicarboxylate: 2Fe3+ + R2-C(OH)-CO− 2 → 2Fe2+ + R2-C=O + H+ + CO 2 where -R represents the group -CH 2CO− 2. This reaction

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    2: Meaning of 2 in the acronym 2fe2 means: undefined

    F: Meaning of F in the acronym 2fe2 means: The letter F is like the letter E, but without the bottom rung. Even without this rung, F shows remarkable stability on its single leg. It means devotion, loving, uncomplaining, defensive, calm. F stands up straights and exemplifies straightforwardness, accountability and harmoniousness.

    E: Meaning of E in the acronym 2fe2 means: The letter E has three branches of equal lenghts. These all extend from it's left side. The equal lenghts show a degree of fairness to the outside world. They extend outwards indicating a willingness to learn, think broadly and be more vigorous in understanding. B also implies endowed with good writing abilities, eloquence, resourcefulness. It displays a unique artistic nature and strong enthusaism to get out and know more.

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