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Epimer

In stereochemistry, an epimer is one of a pair of diastereomers. The two epimers have opposite configuration at only one stereogenic center out of at least

UDP-N,N'-diacetylbacillosamine 2-epimerase (hydrolysing)

enzyme with systematic name UDP-N,N'-diacetylbacillosamine hydrolase (2-epimerising). This enzyme catalyses the following chemical reaction UDP-N,N'-diacetylbacillosamine

UDP-N-acetylglucosamine 2-epimerase (hydrolysing)

enzyme with systematic name UDP-N-acetyl-alpha-D-glucosamine hydrolase (2-epimerising). This enzyme catalyses the following chemical reaction

Alpha-methylacyl-CoA racemase

an anti-inflammatory effect. Human AMACR 1A has been demonstrated to epimerise other 2-APA-CoA esters, suggesting a common chiral inversion pathway for

Histrionicotoxins

then performed under basic conditions at low temperature, successfully epimerising this compound to give the desired epimer 141. A reaction with triphenylphosphine